C₅H₄NCH₂N((CH₂)3NHCH₂C₆H₄OH)2

Base Information

• Chemical Name: C₅H₄NCH₂N((CH₂)3NHCH₂C₆H₄OH)2
• CAS No.: 187587-11-7
• Molecular Formula: C₂₆H₃₄N₄O₂
• Molecular Weight: 434.582
• Mol file: 187587-11-7.mol

Synonyms:

Chemical Property of C₅H₄NCH₂N((CH₂)3NHCH₂C₆H₄OH)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₅H₄NCH₂N((CH₂)3NHCH₂C₆H₄OH)2

There total 1 articles about C₅H₄NCH₂N((CH₂)3NHCH₂C₆H₄OH)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H30N4O2 → C5H4NCH2N((CH2)3NHCH2C6H4OH)2 (187587-11-7)

Guidance literature:

With sodium tetrahydroborate; In ethanol; for 2h; Ambient temperature;

DOI:10.1039/a605706c

Reference yield: 63.0%

zinc(II) tetrafluoroborate monohydrate + sodium tetraphenyl borate (143-66-8) + C5H4NCH2N((CH2)3NHCH2C6H4OH)2 (187587-11-7) → Zn(C26H33N4O2)(1+)*B(C6H5)4(1-)*H2O = [Zn(C26H33N4O2)]B(C6H5)4*H2O (187587-22-0)

Guidance literature:

With NEt₃; In ethanol; refluxing the Zn salt, NEt3 and the ligand in EtOH (3 h), addn. of NaBPh4, further reflux (2 h); recrystn. (EtOH), drying (SiO2/MgSO4, overnight); elem. anal.;

DOI:10.1039/a605706c

Reference yield: 60.0%

copper(II) tetrafluoroborate monohydrate + C5H4NCH2N((CH2)3NHCH2C6H4OH)2 (187587-11-7) → [6-(2-pyridylmethyl)-2,6,10-triazaundecane-1,11-diylbis(2-phenolato)(1-)]copper(II) tetrafluoroborate

Guidance literature:

With Et₃N]; In methanol; refluxing 1.5 equiv. of Cu-salt with 1 equiv. of ligand and 2 equiv. Et3N for 1 h; evapn., dissoln. in MeOH/EtOAc=1:5, crystn. (room temp., overnight), recrystn. (MeCN/EtOAc); elem. anal.;

DOI:10.1107/S0108270196012978

Downstream raw materials:

Zn(C₂₆H₃₃N₄O₂)⁽¹⁺⁾*BF₄^(1-) = [Zn(C₂₆H₃₃N₄O₂)]BF₄

Zn(C₂₆H₃₃N₄O₂)⁽¹⁺⁾*B(C₆H₅)4^(1-)*H₂O = [Zn(C₂₆H₃₃N₄O₂)]B(C₆H₅)4*H₂O

Zn(C₂₆H₃₃N₄O₂)⁽¹⁺⁾*ClO₄^(1-)*CH₃CO₂C₂H₅ = [Zn(C₂₆H₃₃N₄O₂)]ClO₄*CH₃CO₂C₂H₅