[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

Base Information

Chemical Name:[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)
CAS No.:214962-08-0
Molecular Formula:C₇₆H₉₀N₄O₂Zn
Molecular Weight:1156.97
Hs Code.:

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Chemical Property of [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

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Technology Process of [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

There total 4 articles about [2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin-2,3-dione

: 5970-45-6
zinc(II) acetate dihydrate

: 214962-08-0
[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

Guidance literature:: In methanol; dichloromethane; a mixt. of a ligand (0.290 mmol) and Zn(OAc)2*2H2O (1.33 mmol) in CH2Cl2and MeOH was heated at reflux for 3 h; the solvent was removed and the residue purified by column chromy. over flash silica (CH2Cl2-light petroleum);
DOI:10.1039/b211015f

Reference yield: 78.0%

: 332110-41-5
Zn(((CH₃)3C)2C₆H₃C)4(C₄H₂N)3C₄N(NO₂)2

: 214962-08-0
[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

Guidance literature:: With Dess-Martin periodane; In dichloromethane; addn. of Dess-Martin periodinane to a soln. of zinc complex in CH2Cl2, stirring at room temp. in the dark for 25 min; passing through a plug of silica (CH2Cl2), evapn., column chromy (SiO2, CH2Cl2/light petroleum 2:3);
DOI:10.1039/b007389j

Reference yield: 57.0%

: 214962-06-8
[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]zinc(II)

: 214962-08-0
[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]zinc(II)

Guidance literature:: With Dess-Martin periodane; In dichloromethane; periodinane addn. to Zn-compd. soln., mixt. stirring at room temp. in dark for 0.5 h, filtration (silica plug), solvent complete removal; residue chromy. (silica, DCM/light petroleum 1:1);