Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)

Base Information

Chemical Name:Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)
CAS No.:586945-07-5
Molecular Formula:C₅₅H₄₇IOP₂Pd
Molecular Weight:1019.25
Hs Code.:

Pd((R)-Tol-Binap)(o-MeOC<sub>6</sub>H<sub>4</sub>)(I)

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Chemical Property of Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)

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Technology Process of Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)

There total 1 articles about Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 153305-67-0,100165-88-6,99646-28-3
(R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl

: 586945-08-6
(Pd[P(o-Tol)3](o-MeOC6H4)(μ-I))2

: 586945-07-5
Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)

Guidance literature:: In toluene; under N2; soln. of (R)-Tol-Binap in toluene added to suspn. of the Pd complex in toluene; suspn. stirred at room temp. for 24-30 h; soln. filtered by cannula; filtrate pumped dry; solid washed with petroleum ether; trituration with ether; solid collected and recrystd. from THF/petroleum ether at -25 °C; elem. anal.;
DOI:10.1021/om030144x

Reference yield:

: 153305-67-0,100165-88-6,99646-28-3
(R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl

: 501381-03-9,119186-75-3,136172-50-4
(+/-)-methylphenylphosphane borane

: 586945-07-5
Pd((R)-Tol-Binap)(o-MeOC₆H₄)(I)

: 129212-59-5,97764-41-5,97858-63-4
(R(P))-(o-anisyl)(methyl)(phenyl)phosphine-P-borane

: Pd((R)-Tol-Binap)2

Guidance literature:: With NaOSiMe₃; In tetrahydrofuran; under N2; at room temp.; soln. of PH(Me)(Ph)(BH3) and NaOSiMe3 in THF transferred to soln. of Pd((R)-Tol-Binap)(o-An)(I) and (R)-Tol-Binap in THF; not isolated; NMR;
DOI:10.1021/om030144x