(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

Base Information

Chemical Name:(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl
CAS No.:579505-01-4
Molecular Formula:C₃₅H₃₉ClNNiP
Molecular Weight:598.818
Hs Code.:

Synonyms:

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Chemical Property of (η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

Chemical Property:

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Technology Process of (η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

There total 1 articles about (η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 579505-33-2
N-(1-indenylethyl)diisopropylamine

: 579505-01-4
(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

Guidance literature:: With BuLi; In diethyl ether; under N2; Et2O soln. of ligand and soln. of BuLi in hexane stirred at room temp. for 16 h; transferred dropwise over 2 h to stirred slurry of Nicomplex in Et2O; filtered; filtrate vol. reduced; cooled to -15°C; powder isolatedafter multiple pptn. from cold ether and washings with hot hexanes; ele m. anal.;
DOI:10.1021/om030241q

Reference yield:

: 579505-01-4
(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

: 143-66-8
sodium tetraphenyl borate

: 579505-10-5
[(η3:η1-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)][BPh4]

: 579505-12-7
[(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)2][BPh4]

Guidance literature:: In dichloromethane; under N2; CH2Cl2 soln. of Ni complex and NaBPh4 stirred for 4 h; filtered; evapd.; dissolved in CH2Cl2; pptd. by adding hexanes; detd. by(31)P NMR spectra; mixt. of two Ni complexes obtained;
DOI:10.1021/om030241q

Reference yield:

: 579505-01-4
(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)Cl

: 143-66-8
sodium tetraphenyl borate

: 603-35-0
triphenylphosphine

: 579505-12-7
[(η3:η0-N-(1-indenylethyl)diisopropylamine)nickel(PPh3)2][BPh4]

Guidance literature:: In dichloromethane; under N2; Ni complex, PPh3 and NaBPh4 (molar ratio 1:8.6:6.25) in CH2Cl2stirred for 4 h; filtered; evapd.; dissolved in CH2Cl2; pptd. by adding hexanes; detd. by(31)P NMR spectra;
DOI:10.1021/om030241q