trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV)

Base Information

• Chemical Name: trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV)
• CAS No.: 676364-12-8
• Molecular Formula: C₂₄H₁₉F₁₆IN₂Pt
• Molecular Weight: 961.387
• Mol file: 676364-12-8.mol

Synonyms:

Chemical Property of trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV)

There total 1 articles about trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(3,5-(CF3)2C6H3-N=C(CH3)-C(CH3)=N-3,5-(CF3)2C6H3)Pt(II)(CH3)2 (222736-30-3) + 1-iodo-1,2,2,2-tetrafluoroethane (3831-49-0) → trans-[1,2-bis(3,5-bis(trifluoromethyl)phenylimino)-1,2-dimethylethane]iododimethyl(1H-tetrafluoroethyl)platinum(IV) (676364-12-8)

Guidance literature:

In ethyl acetate; under N2 atm. to son. Pt complex in EtOAc ICHFCF3 was added and heated at reflux for 2 h in the absence of light; react. mixt. was cooled, solvent was removed in vacuo, residue was extd.with hot hexane, concd. in vacuo and cooled to -30°C; elem. anal .;

DOI:10.1139/v03-117

upstream raw materials:

(3,5-(CF₃)2C₆H₃-N=C(CH₃)-C(CH₃)=N-3,5-(CF₃)2C₆H₃)Pt(II)(CH₃)2

1-iodo-1,2,2,2-tetrafluoroethane