Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

Base Information

Chemical Name:Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester
CAS No.:105086-97-3
Molecular Formula:C₃₉H₄₄O₉S₂
Molecular Weight:720.905
Hs Code.:

Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

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Chemical Property of Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

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Technology Process of Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

There total 7 articles about Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 104995-62-2
Toluene-4-sulfonic acid (E)-3-{(5R,6R)-4-methoxy-3-[(1S,2S)-1-methyl-2-((E)-1-methyl-3-phenylsulfanyl-propenyl)-cyclohex-3-enecarbonyl]-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

: 105086-97-3
Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00374a050

Reference yield:

: 4124-41-8
p-toluenesulfonylanhydride

: 105086-97-3
Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N / CH₂Cl₂

2: MCPBA / CH₂Cl₂

With triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00374a050

Reference yield:

: 98993-13-6,99094-70-9,111138-05-7
(E)-3-(6-Formyl-6-methyl-cyclohex-2-enyl)-but-2-enoic acid methyl ester

: 105086-97-3
Toluene-4-sulfonic acid (E)-3-{(5R,6R)-3-[(1S,2S)-2-((E)-3-benzenesulfonyl-1-methyl-propenyl)-1-methyl-cyclohex-3-enecarbonyl]-4-methoxy-2-oxo-1-oxa-spiro[4.5]deca-3,8-dien-6-yl}-2-methyl-allyl ester

Guidance literature:: Multi-step reaction with 4 steps

3: Et₃N / CH₂Cl₂

4: MCPBA / CH₂Cl₂

With triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jo00374a050