1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid

Base Information

• Chemical Name: 1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid
• CAS No.: 46913-72-8
• Molecular Formula: C₁₆H₁₂O₂
• Molecular Weight: 236.27
• Mol file: 46913-72-8.mol

Synonyms:

Chemical Property of 1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid

There total 1 articles about 1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(furan-2-yloxy)-trimethylsilane (61550-02-5) + benzo[f]phthalazine (229-72-1) → 1a,9c-dihydro-1H-cyclopropa[c]phenanthrene-1-carboxylic acid + 1a,9a-dihydro-1H-cyclopropa[a]phenanthrene-1-carboxylic acid (21754-11-0,46913-72-8)

Guidance literature:

With 9,10-dimethyl-9,10-dibora-9,10-dihydroanthracene; In diethylene glycol dimethyl ether; at 160 ℃; for 72h; Overall yield = 83 %; Overall yield = 115 mg; Inert atmosphere;

DOI:10.1021/ja308858y

upstream raw materials:

(furan-2-yloxy)-trimethylsilane

benzo[f]phthalazine