Cp(CO)(triphenylphosphite)Mo*CBu

Base Information

• Chemical Name: Cp(CO)(triphenylphosphite)Mo*CBu
• CAS No.: 213621-42-2
• Molecular Formula: C₂₉H₂₉MoO₄P
• Molecular Weight: 568.461
• Mol file: 213621-42-2.mol

Synonyms:

Chemical Property of Cp(CO)(triphenylphosphite)Mo*CBu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cp(CO)(triphenylphosphite)Mo*CBu

There total 1 articles about Cp(CO)(triphenylphosphite)Mo*CBu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cl(CO)2(triphenylphosphite)2Mo*CBu (227608-68-6) + Cl(CO)(triphenylphosphite)3Mo*CBu (227608-69-7) + sodium cyclopentadienide → Cp(CO)(triphenylphosphite)Mo*CBu (213621-42-2)

Guidance literature:

In tetrahydrofuran; inert atmosphere; addn. of NaCp to soln. of mixt. of Mo-complexes, stirring for 3 h at room temp.; evapn., chromy. (Al2O3, Et2O, -78°C), evapn., 3xchromy. (hexane:Et2O 4:1, -78°C); NMR-spectroscopy, overall yield 18.6% (based on Mo(CO)6);

DOI:10.1021/om990047x

Reference yield: 51.0%

triphenyl phosphite (101-02-0) + acetylferrocenium tetrafluoroborate + Cp(CO)(triphenylphosphite)Mo*CBu (213621-42-2) + phenylacetylene (536-74-3) → [(η(5)-C5H5)(CO)(P(OPh)3)Mo[η(1):η(2)-CH(P(OPh)3)C(Ph)=CH(CH2CH2CH2CH3)]]BF4 (213702-31-9,213621-49-9)

Guidance literature:

In dichloromethane; byproducts: acetylferrocene; -90°C to room temp.; evapn. (vac.), extg. (ether), CH2Cl2 addn., pptn. on ether addn., filtering, recrystn. (CH2Cl2 / ether);

DOI:10.1021/om980534x

Reference yield: 28.1%

triphenyl phosphite (101-02-0) + acetylferrocenium tetrafluoroborate + Cp(CO)(triphenylphosphite)Mo*CBu (213621-42-2) + hex-1-yne (693-02-7) → [(η(5)-C5H5)(CO)(P(OPh)3)Mo[η(1):η(2)-CH(P(OPh)3)C(CH2CH2CH2CH3)=CH(CH2CH2CH2CH3)]]BF4 (213702-35-3,213621-55-7)

Guidance literature:

In dichloromethane; byproducts: acetylferrocene; -95 to -78°C (20 min); evapn. (vac., room temp.), , extg. (ether), CH2Cl2 addn., pptn. on hexane addn., CH2Cl2 addn., pptn. on ether addn., recrystn. (CH2Cl2 / hexanes);

DOI:10.1021/om980534x

upstream raw materials:

Cl(CO)2(triphenylphosphite)2Mo*CBu

Cl(CO)(triphenylphosphite)3Mo*CBu

Downstream raw materials:

[Cp(CO)(triphenylphosphite)Mo=CHBu]BF₄

[(η(5)-C5H5)(CO)(P(OPh)3)Mo[η(1):η(2)-CH(P(OPh)3)C(CH2CH2CH2CH3)=CH(CH2CH2CH2CH3)]]BF4

[(η(5)-C5H5)(CO)(P(OPh)3)Mo[η(1):η(2)-CH(P(OPh)3)C(Ph)=CH(CH2CH2CH2CH3)]]BF4