1-Bromo-2-methyl-1-nitrocyclohexane

Base Information

• Chemical Name: 1-Bromo-2-methyl-1-nitrocyclohexane
• CAS No.: 106334-40-1
• Molecular Formula: C₇H₁₂BrNO₂
• Molecular Weight: 222.082
• DSSTox Substance ID: DTXSID50547157
• Mol file: 106334-40-1.mol

Synonyms:1-Bromo-2-methyl-1-nitrocyclohexane;106334-40-1;DTXSID50547157

Chemical Property of 1-Bromo-2-methyl-1-nitrocyclohexane

Chemical Property:

• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 221.00514
• Heavy Atom Count: 11
• Complexity: 168

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CCCCC1([N+](=O)[O-])Br

Technology Process of 1-Bromo-2-methyl-1-nitrocyclohexane

There total 1 articles about 1-Bromo-2-methyl-1-nitrocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1-bromo-1-nitro-2-methylcyclohexane (106334-40-1)

Guidance literature:

With N-Bromosuccinimide; sodium hydrogencarbonate; Behandeln des Reaktionsprodukts mit Salpetersaeure;

DOI:10.1021/ja01112a049

Reference yield: 54.0%

1-bromo-1-nitro-2-methylcyclohexane (106334-40-1) → 2-Methyl-1-nitrocyclohexane (74221-86-6)

Guidance literature:

With sodium tetrahydroborate;

DOI:10.1016/S0040-4020(01)87381-6

Reference yield:

1-bromo-1-nitro-2-methylcyclohexane (106334-40-1) → 1-chloro-2-methyl-1-nitrocyclohexane (75107-62-9)

Guidance literature:

With N-chloro-succinimide; sodium methylate; ethanethiol; Yield given. Multistep reaction; 1.) MeOH, 25 deg C, 15 min, 2.) room temp., 30 min;

DOI:10.1055/s-1986-31791

Downstream raw materials:

2-Methyl-1-nitrocyclohexane

1-chloro-2-methyl-1-nitrocyclohexane

cis-1-Methyl-2-nitro-cyclohexan

trans-1-Methyl-2-nitro-cyclohexan