Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C₆H₅)

Base Information

• Chemical Name: Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C₆H₅)
• CAS No.: 221676-01-3
• Molecular Formula: C₃₂H₄₉BrFeP₂Pd
• Molecular Weight: 737.86
• Mol file: 221676-01-3.mol

Synonyms:

Chemical Property of Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C₆H₅)

There total 1 articles about Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.7%

1,1'-bis(di-tertbutylphosphino)ferrocene (84680-95-5) + [Pd(C6H5)(tris-(o-tolyl)phosphane)Br]2 (232599-87-0) → Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C6H5) (221676-01-3)

Guidance literature:

In tetrahydrofuran; under N2 atm. D-t-BPF in THF was added to soln. Pd complex in THF and stirred for 0.5 h; solvent was removed in vacuo, residue was dissolved in benzene, pentane was added, ppt. was filtered and washed with pentane;

DOI:10.1021/om030230x

Reference yield: 30.0%

Pd(1,1'-bis(di-tert-butylphosphino)ferrocene)(Br)(C6H5) (221676-01-3) + potassium p-methoxyphenolate (1122-93-6) → Pd(1,1'-bis(di-tert-butylphosphinoferrocene)(C6H5)(OC6H4-4-OMe) (223655-15-0)

Guidance literature:

In tetrahydrofuran; under N2 atm. to soln. Pd complex in THF KOC6H4-4-OMe was added and stirred for 1 h; solvent was removed in vacuo, residue was dissolved in pentane, soln. was filtered and concd. to dryness in vacuo, toluene soln. was layered with pentane at -35°C; elem. anal.;

DOI:10.1021/om030230x

upstream raw materials:

1,1'-bis(di-tertbutylphosphino)ferrocene

[Pd(C₆H₅)(tris-(o-tolyl)phosphane)Br]2

Downstream raw materials:

Pd(1,1'-bis(di-tert-butylphosphinoferrocene)(C₆H₅)(OC₆H₄-4-OMe)

Refernces