C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*Br^(1-)*0.5H₂O=C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NHBr*0.5H₂O

Base Information

• Chemical Name: C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*Br^(1-)*0.5H₂O=C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NHBr*0.5H₂O
• CAS No.: 104489-87-4
• Molecular Formula: Br*C₁₇H₁₉FeNO₄P*0H₂O
• Molecular Weight: 477.075
• Mol file: 104489-87-4.mol

Synonyms:

Chemical Property of C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*Br^(1-)*0.5H₂O=C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NHBr*0.5H₂O

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*Br^(1-)*0.5H₂O=C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NHBr*0.5H₂O

There total 1 articles about C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*Br^(1-)*0.5H₂O=C₅H₅Fe(CO)2P(C₆H₅)(OCH₂CH₂)2NHBr*0.5H₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

dicarbonylcyclopentadienylbromoiron(II) + 8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole (57680-64-5) → C5H5Fe(CO)2P(C6H5)(OCH2CH2)2NH(1+)*Br(1-)*0.5H2O=C5H5Fe(CO)2P(C6H5)(OCH2CH2)2NHBr*0.5H2O (104489-87-4) + C5H5Fe(CO)P(C6H5)(OCH2CH2)2NH(1+)*Br(1-)=C5H5Fe(CO)P(C6H5)(OCH2CH2)2NHBr (104489-89-6)

Guidance literature:

In tetrahydrofuran; Ar atmpshere, strirring (room temp., 2 d); filtration, washing (THF), drying (vac.), removal THF from filtrate, recrystn. (toluene), washing (ether); elem. anal.;

Reference yield: 30.0%

C5H5Fe(CO)2P(C6H5)(OCH2CH2)2NH(1+)*Br(1-)*0.5H2O=C5H5Fe(CO)2P(C6H5)(OCH2CH2)2NHBr*0.5H2O (104489-87-4) + sodium tetraphenyl borate (143-66-8) → C5H5Fe(CO)P(C6H5)(OCH2CH2)2NH(1+)*B(C6H5)4(1-)=C5H5Fe(CO)P(C6H5)(OCH2CH2)2NHB(C6H5)4 (104489-86-3)

Guidance literature:

In ethanol; dichloromethane; water; Irradiation (UV/VIS); Ar atmpshere, addn. of CH2Cl2 soln. of Fe-compd. to EtOH soln. of NaBPh4 (strirring, 4 h), addn. of NaBPh4 and water, stirring (1 d), sepn. org. layer, washing (water), removal solvent, drying (vac.), redissoln. in CH2Cl2, UV irradiation (5 h); removal solvent, recrystn. (THF, -30°C), filtration, washing (THF, ether);

upstream raw materials:

8-Phenyl-tetrahydro-8λ⁵-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

Downstream raw materials:

C₅H₅Fe(CO)P(C₆H₅)(OCH₂CH₂)2NH⁽¹⁺⁾*B(C₆H₅)4^(1-)=C₅H₅Fe(CO)P(C₆H₅)(OCH₂CH₂)2NHB(C₆H₅)4

Refernces