RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*ClO₄^(1-)=(RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3)ClO₄

Base Information

• Chemical Name: RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*ClO₄^(1-)=(RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3)ClO₄
• CAS No.: 106587-15-9
• Molecular Formula: C₂₄H₃₅Cl₂OP₃Rh*ClO₄
• Molecular Weight: 705.725

Synonyms:

Chemical Property of RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*ClO₄^(1-)=(RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3)ClO₄

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Technology Process of RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*ClO₄^(1-)=(RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3)ClO₄

There total 2 articles about RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*ClO₄^(1-)=(RhCl₂(H₂O)(P(CH₃)2(C₆H₅))3)ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mer-RhCl3(PMe2Ph)3 (14882-42-9,16634-10-9,99296-74-9) + silver perchlorate → RhCl2(H2O)(P(CH3)2(C6H5))3(1+)*ClO4(1-)=(RhCl2(H2O)(P(CH3)2(C6H5))3)ClO4 (106587-15-9)

Guidance literature:

With water; In water; acetone; byproducts: AgCl; Rh-complex was treated with 1 equiv of AgClO4 in wet acetone;

DOI:10.1016/S0020-1693(00)85289-5

Reference yield:

mer-RhCl3(PMe2Ph)3 (14882-42-9,16634-10-9,99296-74-9) + silver perchlorate → {(P(CH3)2(C6H5))3Cl2Rh(H2O)}(1+)*ClO4(1-)={(P(CH3)2(C6H5))3Cl2Rh(H2O)}ClO4 (106587-15-9)

Guidance literature:

In acetone; byproducts: AgCl; suspn. was shaken for 40 min; AgCl is filtered off, evapd.; dissolved (CH2Cl2); pptd. (diethyl ether); elem. anal.;

Reference yield:

{(P(CH3)2(C6H5))3Cl2Rh(H2O)}(1+)*ClO4(1-)={(P(CH3)2(C6H5))3Cl2Rh(H2O)}ClO4 (106587-15-9) + cyano(triphenylphosphine)gold(I) → mer-{((PMe2Ph)3Cl2Ir(μ-NC))2Rh}{ClO4}

Guidance literature:

In dichloromethane; byproducts: Au(PPh3)2ClO4; complexes dissolved in CH2Cl2; rapidly formed ((PPh3)Au(CN)RhCl2(PMe2Ph)3)ClO4 detected by NMR spectroscopy; conversion to ((PMe2Ph)3Cl2Rh(NC)2Au)ClO4 within minutes;; complexes not isolated pure but characterized by IR and NMR spectroscopy of mixt.;;

DOI:10.1016/S0277-5387(00)80374-5

upstream raw materials:

mer-RhCl3(PMe2Ph)3

Downstream raw materials:

mer-Rh(C₆H₅P(CH₃)2)3Cl₂SCN

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