Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

Base Information

Chemical Name:Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate
CAS No.:139618-59-0
Molecular Formula:C₁₀H₉BrO₃
Molecular Weight:257.084
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

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Technology Process of Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

There total 1 articles about Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 96-34-4
methyl chloroacetate

: 1122-91-4
4-bromo-benzaldehyde

: methyl cis-3-(4-bromophenyl)glycidate

: 51622-82-3,139618-59-0
Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; Overall yield = 99 percent; Overall yield = 17.82 g;
DOI:10.1016/j.tet.2020.131478

Reference yield: 92.0%

: 51622-82-3,139618-59-0
Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

: Methyl (2R^*,3R^*)-3-(4-bromophenyl)-3-azido-2-hydroxypropanoate

Guidance literature:: With sodium azide; ammonium chloride; In methanol; for 1.5h; Heating;
DOI:10.1002/recl.19921110101

Reference yield:

: 51622-82-3,139618-59-0
Methyl trans-3-(4-bromophenyl)oxirane-2-carboxylate

: 139618-70-5
Methyl trans-3-(4-bromophenyl)aziridine-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / NaN₃, NH₄Cl / methanol / 1.5 h / Heating

2: 1) triphenylphosphine / 1) acetonitrile, r.t., 1 h, 2) reflux, 5 h

With sodium azide; ammonium chloride; triphenylphosphine; In methanol;
DOI:10.1002/recl.19921110101