O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁

Base Information

• Chemical Name: O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁
• CAS No.: 61749-57-3
• Molecular Formula: C₇₅H₈₅N₅O₁₇
• Molecular Weight: 1328.52
• Mol file: 61749-57-3.mol

Synonyms:

Chemical Property of O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁

There total 14 articles about O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (50908-08-2) + 3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl chloride (61769-74-2) → O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-galactopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (61749-57-3,79434-27-8,79434-29-0)

Guidance literature:

With silver(I) 4-methylbenzenesulfonate; In benzene; at 40 ℃; for 72h;

DOI:10.1039/P19810002137

Reference yield:

3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl chloride (22860-43-1) + 1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (50908-08-2) → O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (61749-57-3,79434-27-8,79434-29-0) + O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-β-D-glucopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (61749-57-3,79434-27-8,79434-29-0)

Guidance literature:

With 2,3,5-trimethyl-pyridine; silver(I) 4-methylbenzenesulfonate; In benzene; at 45 - 50 ℃; for 18h; Title compound not separated from byproducts;

DOI:10.1039/P19810002137

Reference yield:

3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl chloride (22860-43-1) + 1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (50908-08-2) → O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (61749-57-3,79434-27-8,79434-29-0) + O-3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-β-D-glucopyranosyl-(1->6)-1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C1 (61749-57-3,79434-27-8,79434-29-0)

Guidance literature:

With 2,3,5-trimethyl-pyridine; silver(I) 4-methylbenzenesulfonate; In benzene; at 45 - 50 ℃; for 18h; Title compound not separated from byproducts;

DOI:10.1039/P19810002137

upstream raw materials:

3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl chloride

1,3,2',6'-tetrakis-N-benzyloxycarbonylgentamine C₁

gentamine C₁

benzyl chloroformate

Downstream raw materials:

O-3-amino-3-deoxy-α-D-galactopyranosyl-(1->6)-gentamine C₁