Rh₂Cl₂(CO)2(eLTTP)

Base Information

• Chemical Name: Rh₂Cl₂(CO)2(eLTTP)
• CAS No.: 115481-95-3
• Molecular Formula: C₂₇H₄₀Cl₂O₂P₄Rh₂
• Molecular Weight: 797.225
• Mol file: 115481-95-3.mol

Synonyms:

Chemical Property of Rh₂Cl₂(CO)2(eLTTP)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Rh₂Cl₂(CO)2(eLTTP)

There total 1 articles about Rh₂Cl₂(CO)2(eLTTP) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di(rhodium)tetracarbonyl dichloride + 3,11-diethyl-6,8-diphenyl-3,6,8,11-tetraphosphatridecane (120231-81-4,120231-83-6,159909-88-3,159909-87-2,115481-93-1) → Rh2Cl2(CO)2(eLTTP) (115481-95-3)

Guidance literature:

In tetrahydrofuran; byproducts: CO; adding eLTTP in THF via a cannula, in dry ice/acetone bath, under inert atmosphere, color changed from yellow to golden-red, flushing N2 while warming, stirring over night; filtration, evaporation (vacuum), recrystn. (evapn.) from THF gave the racemic chiral diastereomer, elem. anal. (from recrystd. (toluene) crystals);

DOI:10.1021/ja00224a061

upstream raw materials:

3,11-diethyl-6,8-diphenyl-3,6,8,11-tetraphosphatridecane