Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe)

Base Information

• Chemical Name: Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe)
• CAS No.: 119567-03-2
• Molecular Formula: C₄₁H₃₄O₉P₂PtRu₃
• Molecular Weight: 1230.95
• Mol file: 119567-03-2.mol

Synonyms:

Chemical Property of Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe)

There total 2 articles about Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

Ru3Pt(μ-H)(μ(4)-η2-CC-t-Bu)(CO)9(COD) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe) (119567-03-2) + Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(dppe) (119593-14-5)

Guidance literature:

In diethyl ether; adding bis(diphenylphosphino)ethane in Et2O to stirred soln. of Ru/Pt-complex in Et2O (N2), immediate color changing from light orange to red, stirring (15 min); removing solvent, chromy. (petroleum ether), Ru3Pt(μ-H)(μ4-η2-CC(t-Bu)(CO)9(dppe) (orange band, recrystn., Et2O, -20°C), Ru3Pt(μ4-η2-CC(H)(t-Bu)(CO)9(dppe) (red band, recrystn., CH2Cl2/petroleum ether, -20°C), elem. anal.;

Reference yield:

Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(dppe) (119593-14-5) → Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe) (119567-03-2)

Guidance literature:

In tetrahydrofuran; room temp., 12 h; EXFAS monitoring of react.; Kinetics;

DOI:10.1039/c39920001456

Reference yield: 92.0%

HBF4*OEt2 + Ru3Pt(μ4-η2-CCH(t-Bu))(CO)9(dppe) (119567-03-2) → {Ru3Pt(μH)(μ4-η2-CCH(t-Bu))(CO)9(dppe)}(1+)BF4(1-) (119567-05-4)

Guidance literature:

In dichloromethane; adding excess of HBF4*Et2O to Ru/Pt-complex in CH2Cl2 (N2); adding Et2O, pptn.; elem. anal.;

upstream raw materials:

Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(dppe)

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

{Ru3Pt(μH)(μ4-η2-CCH(t-Bu))(CO)9(dppe)}(1+)BF4(1-)