(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

Base Information

Chemical Name:(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester
CAS No.:594854-70-3
Molecular Formula:C₃₁H₄₄O₇
Molecular Weight:528.686
Hs Code.:

(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

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Chemical Property of (2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

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Technology Process of (2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

There total 6 articles about (2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 594854-65-6
(2E,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienal

: 594854-70-3
(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: LHMDS / hexamethylphosphoric acid triamide

2: potassium hexamethyldisilazane

3: tetraethylammonium fluoride

4: DMAP; pyridine

With pyridine; dmap; potassium hexamethyldisilazane; tetraethylammonium fluoride; lithium hexamethyldisilazane; In N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/j.bmcl.2003.09.072

Reference yield:

: 594854-64-5
(2E,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dien-1-ol

: 594854-70-3
(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 82 percent / tetrapropylammonium perruthenate; NMO; MS₄A

2: LHMDS / hexamethylphosphoric acid triamide

3: potassium hexamethyldisilazane

4: tetraethylammonium fluoride

5: DMAP; pyridine

With pyridine; dmap; N-methyl-2-indolinone; tetrapropylammonium perruthennate; potassium hexamethyldisilazane; tetraethylammonium fluoride; lithium hexamethyldisilazane; In N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/j.bmcl.2003.09.072

Reference yield:

: 594854-63-4
(2E,7E)-(4S,9S)-4,8-Dimethyl-6-methylene-9-(2-trimethylsilanyl-ethoxymethoxy)-undeca-2,7-dienoic acid ethyl ester

: 594854-70-3
(2R,4R)-4-((2E,7E)-(1R,4S,9S)-9-Acetoxy-1-methoxy-4,8-dimethyl-6-methylene-undeca-2,7-dienyl)-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxolane-4-carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 93 percent / diisobutylaluminum hydride

2: 82 percent / tetrapropylammonium perruthenate; NMO; MS₄A

3: LHMDS / hexamethylphosphoric acid triamide

4: potassium hexamethyldisilazane

5: tetraethylammonium fluoride

6: DMAP; pyridine

With pyridine; dmap; N-methyl-2-indolinone; tetrapropylammonium perruthennate; potassium hexamethyldisilazane; diisobutylaluminium hydride; tetraethylammonium fluoride; lithium hexamethyldisilazane; In N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/j.bmcl.2003.09.072