2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

Base Information

• Chemical Name: 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine
• CAS No.: 1646906-26-4
• Molecular Formula: C₅₇H₄₂N₃O₃P₃
• Molecular Weight: 909.9
• Mol file: 1646906-26-4.mol

Synonyms:

Chemical Property of 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

Chemical Property:

• Melting Point: TGA 460 °C(0.5% weight loss)
• PKA: 0.00±0.10(Predicted)
• Density: 1.35±0.1 g/cm3(Predicted)
• Storage Temp.: 15-25°C

Purity/Quality:

97% ^*data from raw suppliers

((1,3,5-Triazine-2,4,6-triyl)tris(benzene-3,1-diyl))tris(diphenylphosphineoxide) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Description: PO-T2T, namely2,4,6-tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazineis electron deficient with a triazine centre and three diphenylphosphines.
• Uses: PO-T2T is an electron transport/hole blocking material in OLED, or an electron acceptor material in organic electronics.An efficient action of radical-based OLEDs, whose emission originates from a spin doublet, rather than a singlet or triplet exciton was demonstrated in a study published in Nature.While the emission process is still spin-allowed in these OLEDs, the efficiency limitations imposed by triplet excitons are circumvented for doublets. Using a luminescent radical emitter, an OLED with maximum external quantum efficiency of 27% at a wavelength of 710nm-the highest reported value for deep-red and infrared LEDs was achieved. In this very efficient OLEDs, selective hole injection into the HOMO and electron injection to the SOMO was achieved imploying TAPC as the hole transport layer, and PO-T2T as the electron transport layer to form the fluorescent doublet excited state with near-unity internal quantum efficiency.

Technology Process of 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

There total 1 articles about 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C57H42N3P3 → ((1,3,5-triazine-2,4,6-triyl)tris(benzene-3,1-diyl))tris(diphenylphosphine oxide) (1646906-26-4)

Guidance literature:

With dihydrogen peroxide; In dichloromethane; at 0 ℃;

DOI:10.1039/c4tc02993c

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