C₄₃H₄₀O₅P₂Ru

Base Information

• Chemical Name: C₄₃H₄₀O₅P₂Ru
• CAS No.: 1370548-64-3
• Molecular Formula: C₄₃H₄₀O₅P₂Ru
• Molecular Weight: 799.805
• Mol file: 1370548-64-3.mol

Synonyms:

Chemical Property of C₄₃H₄₀O₅P₂Ru

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₄₃H₄₀O₅P₂Ru

There total 1 articles about C₄₃H₄₀O₅P₂Ru which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[Ru(η2-OAc)2(PPh3)2] (26455-80-1,57063-42-0,933789-54-9,40780-26-5) + propargyl alcohol (107-19-7) → trans-Ru(κ1-O2CCH3)(κ2-O2CCH3)(P(C6H5)3)2(CCHC(OH)H2) (1370548-64-3)

Guidance literature:

In dichloromethane; N2 or Ar, Schlenk technique or glovebox; reaction of Ru-complex with alkyne for 1 h at stirring; pentane or hexane added, ppt. isolated by filtration, washed (pentane orhexane, 3 times), dried (vac.); elem. anal.;

DOI:10.1002/ejic.201100931

Reference yield:

C43H40O5P2Ru (1370548-64-3) → [Ru(η1-OAc)(η2-OAc)(PPh3)2(CO)] (142215-87-0,38596-65-5,52746-32-4,61990-12-3) + C59H52O3P3Ru(1+)*BF4(1-) + Trityltriphenylphosphan (48234-64-6)

Guidance literature:

In dichloromethane-d2; at 20 ℃; Inert atmosphere;

DOI:10.1021/om4009247

Reference yield:

trans-Ru(κ1-O2CCH3)(κ2-O2CCH3)(P(C6H5)3)2(CCHC(OH)H2) (1370548-64-3) → [Ru(η2-OAc)2(PPh3)2] (26455-80-1,57063-42-0,933789-54-9,40780-26-5)

Guidance literature:

In dichloromethane-d2; byproducts: H2CCH2; N2 or Ar; detd. by NMR;

DOI:10.1002/ejic.201100931

upstream raw materials:

[Ru(η²-OAc)₂(PPh₃)₂]

propargyl alcohol

Downstream raw materials:

[Ru(η²-OAc)₂(PPh₃)₂]

[Ru(η¹-OAc)(η²-OAc)(PPh₃)₂(CO)]

Trityltriphenylphosphan