tert-butyl(diferrocenyl)phosphine

Base Information

Chemical Name:tert-butyl(diferrocenyl)phosphine
CAS No.:426847-29-2
Molecular Formula:C₂₄H₂₇Fe₂P
Molecular Weight:458.146
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-butyl(diferrocenyl)phosphine

Chemical Property:

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Technology Process of tert-butyl(diferrocenyl)phosphine

There total 1 articles about tert-butyl(diferrocenyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

: 102-54-5,55404-68-7
ferrocene

: 25979-07-1
tert-butyldichlorophosphine

: 426847-29-2
tert-butyl(diferrocenyl)phosphine

: diferrocenyl(t-buthyl)phosphine oxide * 1/3 benzene

Guidance literature:: With AlCl₃; In hexane; under N2; ferrocene and AlCl3 stirred, slightly warmed, cooled to room temp.; (CH3)3CPCl2 added dropwise under stirring; refluxed for 48 h; cooled; ppt. extd. (hot hexane); residue washed with boiling, de-ionized, de-gassed water; extd. (hot benzene); ext. dried (Na2SO4), filtered; solvent removed (vac.); chromy. (alumina/phosphine (benzene), phosphine oxide (CHCl3)); solvent evapd.; elem. anal.;
DOI:10.1081/SIM-120013149

Reference yield: 86.0%

: 426847-29-2
tert-butyl(diferrocenyl)phosphine

: 84-58-2
2,3-dicyano-5,6-dichloro-p-benzoquinone

: [(diferrocenyl)(tert-butyl)phosphine(+)][2,3-dichloro-5,6-dicyano-1,4-benzoquinone(-)]

Guidance literature:: In benzene; under Ar or N2 atm. using Schlenk techniques; soln. of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in C6H6 added dropwise to soln. of phosphine inbenzene at ambient temp.; suspn. stirred for 2 h; supernatant decanted; powder washed (benzene, hexane); dried (vac.); elem. anal.;
DOI:10.1016/S0020-1693(03)00387-6