dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

Base Information

• Chemical Name: dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)
• CAS No.: 124273-54-7
• Molecular Formula: C₅₀H₅₁NO₁₂PRh
• Molecular Weight: 991.834
• Mol file: 124273-54-7.mol

Synonyms:

Chemical Property of dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

There total 9 articles about dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Natrium-<3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)>pyrrolat → dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) (124273-54-7)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran

2: triphenyl phosphine / tetrahydrofuran

3: CO / dichloromethane

With triphenyl phosphine; CO; In tetrahydrofuran; dichloromethane;

Reference yield:

(η4-bicyclo{2.2.1}hepta-2,5-diene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethyl-furan-2-yl-methyl)pyrrolato-N}(triphenylphosphine)rhodium(I) (124273-50-3) → dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) (124273-54-7)

Guidance literature:

With CO; In dichloromethane; introduction of dry CO-stream in soln. of Rh-complex in CH2Cl2 (-40°C); not isolated; IR, (1)H-NMR, (13)C-NMR, (31)P((1)H)-NMR;

Reference yield:

(η4-1,5-cyclooctadiene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) (124273-49-0) → dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I) (124273-54-7)

Guidance literature:

With CO; In dichloromethane; introduction of dry CO-stream in soln. of Rh-complex in CH2Cl2 (-40°C); not isolated; IR, (1)H-NMR, (13)C-NMR, (31)P((1)H)-NMR;

upstream raw materials:

(η4-1,5-cyclooctadiene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

(η4-bicyclo{2.2.1}hepta-2,5-diene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethyl-furan-2-yl-methyl)pyrrolato-N}(triphenylphosphine)rhodium(I)

carbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

(η4-1,5-cyclooctadiene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}rhodium(I)