1,10-Phenanthroline-5-carbonitrile

Base Information

Chemical Name:1,10-Phenanthroline-5-carbonitrile
CAS No.:1082-21-9
Molecular Formula:C13H7N3
Molecular Weight:205.21500
Hs Code.:2933990090
DSSTox Substance ID:DTXSID60357582
Nikkaji Number:J695.018C
Wikidata:Q82137541
Mol file:1082-21-9.mol

Synonyms:1,10-phenanthroline-5-carbonitrile;1082-21-9;Oprea1_064189;SCHEMBL11908005;DTXSID60357582;BAA08221;AKOS000275023;CS-W004556;A907618;Z56777688

Suppliers and Price of 1,10-Phenanthroline-5-carbonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
1,10-Phenanthroline-5-carbonitrile 95+%
1g
$ 518.00

Arctom
1,10-Phenanthroline-5-carbonitrile 98%
1g
$ 414.00

American Custom Chemicals Corporation
PYRIDINO[3,2-H]QUINOLINE-5-CARBONITRILE 95.00%
5MG
$ 505.43

Alichem
1,10-Phenanthroline-5-carbonitrile
1g
$ 443.10

Total 11 raw suppliers

Chemical Property of 1,10-Phenanthroline-5-carbonitrile

Chemical Property:

Melting Point:212-213 °C
Boiling Point:445.3±25.0 °C(Predicted)
PKA:3.69±0.10(Predicted)
PSA：49.57000
Density:1.33±0.1 g/cm3(Predicted)
LogP:2.65468
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:205.063997236
Heavy Atom Count:16
Complexity:306

Purity/Quality:

97% ^*data from raw suppliers

1,10-Phenanthroline-5-carbonitrile 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC2=CC(=C3C=CC=NC3=C2N=C1)C#N
General Description 1,10-Phenanthroline-5-carbonitrile is a substituted phenanthroline derivative featuring a cyano group at the 5-position, which serves as an electron-withdrawing ligand in ruthenium(II) complexes. It influences the optical and redox properties of these complexes, contributing to tunable photo-physical characteristics such as absorption and two-photon absorption cross-sections in the near-infrared range. This ligand is part of broader studies on modifying 1,10-phenanthroline-based systems for applications in photophysical and electrochemical devices.

Technology Process of 1,10-Phenanthroline-5-carbonitrile

There total 5 articles about 1,10-Phenanthroline-5-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: potassium cyanide

: 40000-20-2
5-bromo-1,10-phenanthroline

: 1082-21-9
5-cyano-1,10-phenanthroline

Guidance literature:: In water; at 20 ℃; for 4h;
DOI:10.1128/AAC.00969-17

Reference yield: 55.0%

: potassium cyanide

: 65115-91-5
5,6-epoxy-5,6-dihydro-[1,10]phenanthroline

: 1082-21-9
5-cyano-1,10-phenanthroline

Guidance literature:: With commercial bleach; at 20 ℃;
DOI:10.1039/d1dt00886b

Reference yield:

: 66-71-7
1,10-Phenanthroline

: 1082-21-9
5-cyano-1,10-phenanthroline

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hypochlorite; tetra(n-butyl)ammonium hydrogensulfate / 2 h / 18 °C / pH 8.5

2: water / 4 h

With sodium hypochlorite; tetra(n-butyl)ammonium hydrogensulfate; In water;
DOI:10.1039/c7cc02878d