Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin

Base Information

• Chemical Name: Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin
• CAS No.: 1021946-43-9
• Molecular Formula: C₃₁H₂₆CuN₄O₂
• Molecular Weight: 550.119
• Mol file: 1021946-43-9.mol

Synonyms:

Chemical Property of Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin

There total 1 articles about Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

5-(1,5-dihydroxypent-3-yl)-15-phenylprophyrin + copper diacetate (142-71-2) → Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin (1021946-43-9)

Guidance literature:

In methanol; chloroform; porphyrin in CHCl3-MeOH treated with Cu acetate (10 equiv.); stirred at room temp. for 12 h; diluted with ethyl acetate and H2O; aq. layer extd. with ethyl acetate; org. layer dried (Na2SO4); chromd. (neutral alumina, CH2Cl2 to CH2Cl2-MeOH-THF 5:1:1);

DOI:10.1039/b714127k

Reference yield: 35.0%

Cu(II)-5-(1,5-dihydroxypent-3-yl)-15-phenylporphyrin (1021946-43-9) + Dimethyl chlorophosphate (813-77-4) → Cu(II)-5-[1,5-bis(dimethoxyphosphoryloxy)pent-3-yl]-15-phenylporphyrin (1021946-44-0)

Guidance literature:

With dmap; In dichloromethane; under Ar; soln. of Cu porphyrin in dry CH2Cl2 treated with DMAP (10 equiv.); stirred at room temp. for 10 min; ClP(O)(OMe)2 added dropwise; stirred at room temp. for 12 h; column chromd. (silica, CH2Cl2 to CH2Cl2-MeOH 97:3);

DOI:10.1039/b714127k

upstream raw materials:

copper diacetate

Downstream raw materials:

Cu(II)-5-[1,5-bis(dimethoxyphosphoryloxy)pent-3-yl]-15-phenylporphyrin