1-trimethylstannyl-3-phenylpropyne

Base Information

Chemical Name:1-trimethylstannyl-3-phenylpropyne
CAS No.:87673-32-3
Molecular Formula:C₁₂H₁₆Sn
Molecular Weight:278.969
Hs Code.:

Synonyms:

Suppliers and Price of 1-trimethylstannyl-3-phenylpropyne

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-trimethylstannyl-3-phenylpropyne

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-trimethylstannyl-3-phenylpropyne

There total 1 articles about 1-trimethylstannyl-3-phenylpropyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10147-11-2
propargyl benzene

: 1213-51-0
(trimethylstannyl)diphenylphosphine

: 87673-32-3
1-trimethylstannyl-3-phenylpropyne

Guidance literature:: With catalyst:AIBN; byproducts: diphenylphosphine; react. of Sn-compd. with acetylene with addn. of catalytic amounts of AIBN at 80°C;
DOI:10.1016/0022-328X(90)85241-P

Reference yield: 74.0%

: 87673-32-3
1-trimethylstannyl-3-phenylpropyne

: 1068-74-2
Diethylamino-trimethyl-stannan

: 145701-68-4
1,1-bis(trimethylstannyl)-3-phenylpropadiene

Guidance literature:: In neat (no solvent); byproducts: NH(C2H5)2; a mixt. of (CH3)3SnCCCH2C6H5 and (CH3)3SnN(C2H5)2 was heated at 140-160°C for 0.1 h under continuous removal of NHEt2 by distn.;; distn.; elem. anal.;;

Reference yield:

: 87673-32-3
1-trimethylstannyl-3-phenylpropyne

: 1631-73-8
trimethylstannane

: 85263-65-6
(CH₃)3SnC(CH₂C₆H₅)CHSn(CH₃)3

: 87673-36-7
C₆H₅CH₂CHC(Sn(CH₃)3)2

Guidance literature:: With catalyst: azobisisobutyronitrile; In neat (no solvent); equimolar amts. of the alkyne and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h (IR and (1)H NMR monitoring); PhCH2CH=C(SnMe3)2 to PhCH2(Me3Sn)C=CHSnMe3 ratio 91:9, total yield 94%; the reaction mixt. was distilled under reduced pressure (b.p. 95°C/0.001 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
DOI:10.1016/0022-328X(83)80057-6