C₃₆H₅₀O₆Si

Base Information

Chemical Name:C₃₆H₅₀O₆Si
CAS No.:1261148-39-3
Molecular Formula:C₃₆H₅₀O₆Si
Molecular Weight:606.875
Hs Code.:

C<sub>36</sub>H<sub>50</sub>O<sub>6</sub>Si

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Chemical Property of C₃₆H₅₀O₆Si

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Technology Process of C₃₆H₅₀O₆Si

There total 16 articles about C₃₆H₅₀O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1227265-23-7
C₃₁H₃₆O₄Si

: 1261148-39-3
C₃₆H₅₀O₆Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: diethyl ether / 1 h / -78 °C / Inert atmosphere

2.1: 20 % Pd(OH)2/C; hydrogen / ethanol; ethyl acetate / 18 h / 25 °C

3.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 18 h / 25 °C / Inert atmosphere

4.1: dichloromethane / 4 h / 25 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / dichloromethane / 1.5 h / -78 - 25 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

7.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (Me₃Sn)2; trifuran-2-yl-phosphane; lithium chloride / tetrahydrofuran / 0.5 h / 25 °C / Inert atmosphere

7.2: 3 h / 40 °C / Inert atmosphere

8.1: Oxone; sodium tetraborate heptahydrate; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; potassium carbonate / Dimethoxymethane; water; acetonitrile / 3 h / 0 °C

9.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 25 °C

10.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

11.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.33 h / 0 °C / Inert atmosphere

11.2: 0.33 h / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; Oxone; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; trifuran-2-yl-phosphane; [bis(acetoxy)iodo]benzene; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; sodium tetraborate heptahydrate; 20 % Pd(OH)2/C; (Me₃Sn)2; hydrogen; tetra(n-butyl)ammonium hydrogensulfate; sodium hexamethyldisilazane; edetate disodium; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; In tetrahydrofuran; diethyl ether; Dimethoxymethane; ethanol; dichloromethane; water; ethyl acetate; toluene; acetonitrile; 1.1: Grignard reaction / 7.2: Stille coupling / 8.1: Shi epoxidation / 11.1: Whiting reaction / 11.2: Whiting reaction;
DOI:10.1021/ja109531d

Reference yield:

: C₅H₉IO

: 1261148-39-3
C₃₆H₅₀O₆Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: Dess-Martin periodane / dichloromethane / 1.5 h / 25 °C / Inert atmosphere

2.1: dichloromethane / 2 h / 25 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

4.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / decane; dichloromethane / 1.5 h / -20 °C / Molecular sieve; Inert atmosphere

5.1: lanthanum(lll) triflate / toluene / 0.33 h / 25 °C / Inert atmosphere

6.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (Me₃Sn)2; trifuran-2-yl-phosphane; lithium chloride / tetrahydrofuran / 0.5 h / 25 °C / Inert atmosphere

6.2: 3 h / 40 °C / Inert atmosphere

7.1: Oxone; sodium tetraborate heptahydrate; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; potassium carbonate / Dimethoxymethane; water; acetonitrile / 3 h / 0 °C

8.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 25 °C

9.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

10.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.33 h / 0 °C / Inert atmosphere

10.2: 0.33 h / 0 °C / Inert atmosphere

With titanium(IV) isopropylate; tert.-butylhydroperoxide; Oxone; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trifuran-2-yl-phosphane; diethyl (2S,3S)-tartrate; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; sodium tetraborate heptahydrate; (Me₃Sn)2; tetra(n-butyl)ammonium hydrogensulfate; sodium hexamethyldisilazane; edetate disodium; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; lanthanum(lll) triflate; In tetrahydrofuran; decane; Dimethoxymethane; dichloromethane; water; toluene; acetonitrile; 2.1: Whiting reaction / 4.1: Sharpless epoxidation / 6.2: Stille coupling / 7.1: Shi epoxidation / 10.1: Whiting reaction / 10.2: Whiting reaction;
DOI:10.1021/ja109531d

Reference yield:

: C₈H₁₁IO₂

: 1261148-39-3
C₃₆H₅₀O₆Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: diisobutylaluminium hydride / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

2.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate / decane; dichloromethane / 1.5 h / -20 °C / Molecular sieve; Inert atmosphere

3.1: lanthanum(lll) triflate / toluene / 0.33 h / 25 °C / Inert atmosphere

4.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; (Me₃Sn)2; trifuran-2-yl-phosphane; lithium chloride / tetrahydrofuran / 0.5 h / 25 °C / Inert atmosphere

4.2: 3 h / 40 °C / Inert atmosphere

5.1: Oxone; sodium tetraborate heptahydrate; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; potassium carbonate / Dimethoxymethane; water; acetonitrile / 3 h / 0 °C

6.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 25 °C

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

8.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.33 h / 0 °C / Inert atmosphere

8.2: 0.33 h / 0 °C / Inert atmosphere

With titanium(IV) isopropylate; tert.-butylhydroperoxide; Oxone; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; trifuran-2-yl-phosphane; diethyl (2S,3S)-tartrate; 1,2:4,5-di(O-i-propylidene)-3-deoxy-3-oxo-β-D-psicopyranose; sodium tetraborate heptahydrate; (Me₃Sn)2; tetra(n-butyl)ammonium hydrogensulfate; sodium hexamethyldisilazane; edetate disodium; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; lanthanum(lll) triflate; In tetrahydrofuran; decane; Dimethoxymethane; dichloromethane; water; toluene; acetonitrile; 2.1: Sharpless epoxidation / 4.2: Stille coupling / 5.1: Shi epoxidation / 8.1: Whiting reaction / 8.2: Whiting reaction;
DOI:10.1021/ja109531d