trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

Base Information

Chemical Name:trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene
CAS No.:122048-44-6
Molecular Formula:C₄₆H₅₈O₆
Molecular Weight:706.963
Hs Code.:

trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzo<g>chrysene

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

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Technology Process of trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

There total 24 articles about trans-11,12-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 15356-62-4
L-menthoxyacetyl chloride

: 122048-32-2,122048-33-3,122090-51-1,122090-52-2
trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene

: 122048-44-6,122090-53-3
trans-11S,12S-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

: 122048-44-6,122090-53-3
trans-11R,12R-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

Guidance literature:: With pyridine; at 0 - 2 ℃; for 22h;
DOI:10.1021/jo00276a009

Reference yield: 81.0%

: 15356-62-4
L-menthoxyacetyl chloride

: 122048-32-2,122048-33-3,122090-51-1,122090-52-2
trans-11,12-dihydroxy-11,12,13,14-tetrahydrobenzochrysene

: 122048-44-6,122090-53-3
trans-11S,12S-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

: 122048-44-6,122090-53-3
trans-11R,12R-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

Guidance literature:: With pyridine; at 0 - 2 ℃; for 22h;
DOI:10.1021/jo00276a009

Reference yield:

: 122048-29-7
13,14-dihydrobenzochrysene

: 122048-44-6,122090-53-3
trans-11S,12S-bis(((-)-menthyloxy)acetoxy)-11,12,13,14-tetrahydrobenzochrysene

Guidance literature:: Multi-step reaction with 3 steps

1: m-chloroperbenzoic acid (m-CPBA), 5percent NaHCO₃ / CH₂Cl₂ / 0.83 h

2: NH₃ / methanol / Ambient temperature

3: 85 percent / pyridine / 22 h / 0 - 2 °C

With pyridine; ammonia; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane;
DOI:10.1021/jo00276a009