1-phenylthiaindan hexafluorophosphate

Base Information

• Chemical Name: 1-phenylthiaindan hexafluorophosphate
• CAS No.: 82136-00-3
• Molecular Formula: C₁₄H₁₃S*F₆P
• Molecular Weight: 358.287
• Mol file: 82136-00-3.mol

Synonyms:

Chemical Property of 1-phenylthiaindan hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenylthiaindan hexafluorophosphate

There total 2 articles about 1-phenylthiaindan hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

racemic 2,3-dihydrobenzo[b]thiophene-1-oxide (26524-83-4) → 1-phenylthiaindan hexafluorophosphate (82136-00-3)

Guidance literature:

Multi-step reaction with 2 steps

2: diethyl ether

In diethyl ether;

DOI:10.1021/ja00380a020

Reference yield:

phenylmagnesium bromide + 1-methoxythiaindan fluoroborate → 1-phenylthiaindan hexafluorophosphate (82136-00-3)

Guidance literature:

In diethyl ether; Yield given;

DOI:10.1021/ja00380a020

Reference yield: 15.3%

1-phenylthiaindan hexafluorophosphate (82136-00-3) → 2,3-dihydrobenzo(b)thiophene (4565-32-6) + 2-ethylphenyl phenyl sulfide (23075-79-8) + 1-(phenylsulfanyl)-2-vinylbenzene (82136-07-0) + C28H26S2

Guidance literature:

With potassium graphite; In tetrahydrofuran; for 1h; Product distribution; Ambient temperature; order of cleavage, cleavage ratio; further reagents (potassium naphthalenide);

DOI:10.1021/ja00380a020

upstream raw materials:

racemic 2,3-dihydrobenzo[b]thiophene-1-oxide

Downstream raw materials:

2,3-dihydrobenzo(b)thiophene

2-ethylphenyl phenyl sulfide

1-(phenylsulfanyl)-2-vinylbenzene