(1-phenylhexan-2-yl)phosphinic acid

Base Information

• Chemical Name: (1-phenylhexan-2-yl)phosphinic acid
• CAS No.: 1536240-42-2
• Molecular Formula: C₁₂H₁₉O₂P
• Molecular Weight: 226.255
• Mol file: 1536240-42-2.mol

Synonyms:

Chemical Property of (1-phenylhexan-2-yl)phosphinic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1-phenylhexan-2-yl)phosphinic acid

There total 2 articles about (1-phenylhexan-2-yl)phosphinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

1-phenylhex-1-ene (6111-82-6,15325-54-9,828-15-9) → (1-phenylhexan-2-yl)phosphinic acid (1536240-42-2) + (1-phenylhexan-2-yl)phosphine

Guidance literature:

1-phenylhex-1-ene; With potassium hydroxide semihydrate; phosphorus; water; In dimethyl sulfoxide; at 120 ℃; for 2.5h; Inert atmosphere;

With hydrogenchloride; In water; at 20 - 25 ℃; pH=1;

DOI:10.1134/S1070428013120233

Reference yield:

1-phenylhexan-1-ol (4471-05-0) → (1-phenylhexan-2-yl)phosphinic acid (1536240-42-2) + (1-phenylhexan-2-yl)phosphine

Guidance literature:

Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid

2.1: water; potassium hydroxide semihydrate; phosphorus / dimethyl sulfoxide / 2.5 h / 120 °C / Inert atmosphere

2.2: 20 - 25 °C / pH 1

With potassium hydroxide semihydrate; phosphorus; water; toluene-4-sulfonic acid; In dimethyl sulfoxide;

DOI:10.1134/S1070428013120233

upstream raw materials:

1-phenylhexan-1-ol

1-phenylhex-1-ene