((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane

Base Information

• Chemical Name: ((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane
• CAS No.: 1446416-56-3
• Molecular Formula: C₁₁H₂₁ISi
• Molecular Weight: 308.278

Synonyms:

Chemical Property of ((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane

Chemical Property:

Purity/Quality:

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Technology Process of ((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane

There total 1 articles about ((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C11H22OSi → ((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane (1446416-56-3) + ((4-iodo-2-methylcyclohex-1-en-1-yl)methyl)trimethylsilane (1446416-57-4)

Guidance literature:

With C₄H₁₀O*I₂Mg; In benzene; at 22 ℃; Overall yield = 68 %; Inert atmosphere;

DOI:10.1021/jo4009854

Reference yield:

((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane (1446416-56-3) → 2,2,3b-trimethyldecahydro-1H-cyclopenta[a]pentalen-1-ol

Guidance literature:

Multi-step reaction with 5 steps

1.1: n-butyllithium; diisopropylamine; N,N,N,N,N,N-hexamethylphosphoric triamide / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere

1.2: 1.5 h / -78 - 20 °C / Inert atmosphere

2.1: N,N,N,N,N,N-hexamethylphosphoric triamide; tetra-n-butylammoniumfluoride trihydrate / N,N-dimethyl-formamide / 12 h / 22 °C / Inert atmosphere; Molecular sieve

3.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / 0 °C / Inert atmosphere

4.1: triethylamine / benzene / 0 - 20 °C / Inert atmosphere

5.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / 0 °C / Inert atmosphere

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; n-butyllithium; tetra-n-butylammoniumfluoride trihydrate; triethylamine; diisopropylamine; In tetrahydrofuran; diethyl ether; hexane; N,N-dimethyl-formamide; benzene;

DOI:10.1021/jo4009854

Reference yield:

((3-(iodomethyl)-2-methylcyclopent-1-en-1-yl)methyl)trimethylsilane (1446416-56-3) → 2,2,3b-trimethyl-4-methylenedecahydro-1H-cyclopenta[a]pentalen-1-ol

Guidance literature:

Multi-step reaction with 4 steps

1.1: n-butyllithium; diisopropylamine; N,N,N,N,N,N-hexamethylphosphoric triamide / tetrahydrofuran; hexane / 0.5 h / -78 - 0 °C / Inert atmosphere

1.2: 1.5 h / -78 - 20 °C / Inert atmosphere

2.1: N,N,N,N,N,N-hexamethylphosphoric triamide; tetra-n-butylammoniumfluoride trihydrate / N,N-dimethyl-formamide / 12 h / 22 °C / Inert atmosphere; Molecular sieve

3.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / 0 °C / Inert atmosphere

4.1: triethylamine / benzene / 0 - 20 °C / Inert atmosphere

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; n-butyllithium; tetra-n-butylammoniumfluoride trihydrate; triethylamine; diisopropylamine; In tetrahydrofuran; diethyl ether; hexane; N,N-dimethyl-formamide; benzene;

DOI:10.1021/jo4009854

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