Technology Process of 2-<(2)H3>methyl-2-methylcyclohexanone
There total 7 articles about 2-<(2)H3>methyl-2-methylcyclohexanone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 68.5 percent / Triton B / methanol / 16 h / 70 °C
2: 66 percent / Kloeckera magna (ATCC 20109), physiol. NaCl sol. / dimethylformamide / 14 h
3: 90 percent / triethylamine / CH2Cl2 / 1 h / 0 °C
4: LiAlH4 / diethyl ether / 1.) 0,5 h, -5 to 0 deg C, 2.) 18 h, room temp.
5: H2 / Pd/BaCO3 (5percent) / ethyl acetate; methanol / Ambient temperature
6: Jones reagent / acetone / 0.5 h / Ambient temperature
With
lithium aluminium tetrahydride; jones reagent; Kloeckera magna (ATCC 20109); hydrogen; N-benzyl-trimethylammonium hydroxide; triethylamine; sodium chloride;
palladium-barium carbonate;
In
methanol; diethyl ether; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo00172a021
- Guidance literature:
-
Multi-step reaction with 2 steps
1: H2 / Pd/BaCO3 (5percent) / ethyl acetate; methanol / Ambient temperature
2: Jones reagent / acetone / 0.5 h / Ambient temperature
With
jones reagent; hydrogen;
palladium-barium carbonate;
In
methanol; ethyl acetate; acetone;
DOI:10.1021/jo00172a021
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 90 percent / triethylamine / CH2Cl2 / 1 h / 0 °C
2: LiAlH4 / diethyl ether / 1.) 0,5 h, -5 to 0 deg C, 2.) 18 h, room temp.
3: H2 / Pd/BaCO3 (5percent) / ethyl acetate; methanol / Ambient temperature
4: Jones reagent / acetone / 0.5 h / Ambient temperature
With
lithium aluminium tetrahydride; jones reagent; hydrogen; triethylamine;
palladium-barium carbonate;
In
methanol; diethyl ether; dichloromethane; ethyl acetate; acetone;
DOI:10.1021/jo00172a021
