[[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium⁽⁰⁾ pentacarbonyl

Base Information

• Chemical Name: [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium⁽⁰⁾ pentacarbonyl
• CAS No.: 135394-63-7
• Molecular Formula: C₂₀H₁₇CrNO₅Si
• Molecular Weight: 431.44
• Mol file: 135394-63-7.mol

Synonyms:

Chemical Property of [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium⁽⁰⁾ pentacarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium⁽⁰⁾ pentacarbonyl

There total 8 articles about [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium⁽⁰⁾ pentacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

([2-[(dimethylamino)methyl]phenyl]hydrosilanediyl)chromium(0) pentacarbonyl (148538-99-2) + phenyllithium (591-51-5) → [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium(0) pentacarbonyl (135394-63-7)

Guidance literature:

In toluene; byproducts: LiH; Ar-atmosphere; stirring (room temp., 24 h); filtering, evapn.;

DOI:10.1021/om00008a056

Reference yield: 68.0%

[2-[(dimethylamino)methyl]phenyl]phenyldihydrosilane + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium(0) pentacarbonyl (135394-63-7)

Guidance literature:

In not given; Irradiation (UV/VIS); Ar-atmosphere; washing (pentane); elem. anal.;

DOI:10.1021/om00004a020

Reference yield: 63.0%

disodium pentacarbonylchromium + SiCl2(C6H4CH2N(CH3)2)(C6H5) (135394-61-5) → [[2-((dimethylamino)methyl)phenyl]phenylsilanediyl]chromium(0) pentacarbonyl (135394-63-7)

Guidance literature:

In tetrahydrofuran; byproducts: NaCl; Na2Cr(CO)5 dissolved in THF (ultrasonication), soln. cooled to -40°C, silane soln. added with stirring, warmed to room temp. and stirred for 3h;; soln. separated from NaCl, concentrated in vac. (5E-2 Torr), crystd. at -20°C;;

upstream raw materials:

phenyllithium

chromium⁽⁰⁾ hexacarbonyl

([2-[(dimethylamino)methyl]phenyl]hydrosilanediyl)chromium⁽⁰⁾ pentacarbonyl

SiCl₂(C₆H₄CH₂N(CH₃)2)(C₆H₅)