3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one

Base Information

Chemical Name:3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one
CAS No.:109773-42-4
Molecular Formula:C₂₇H₁₉N₂O₃P
Molecular Weight:450.433
Hs Code.:
DSSTox Substance ID:DTXSID90547212
Wikidata:Q82425290

Synonyms:109773-42-4;DTXSID90547212;3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one;3-(Triphenylphosphoranylidene)-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one

Suppliers and Price of 3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one

Chemical Property:

XLogP3:5.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:450.11332947
Heavy Atom Count:33
Complexity:756

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1OC2=C(O1)C=C3C(=C2)C(=O)C(=P(C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)N=N3

Technology Process of 3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one

There total 4 articles about 3-(Triphenyl-lambda~5~-phosphanylidene)-7H-[1,3]dioxolo[4,5-g]cinnolin-4(3H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 40680-63-5
methyl 6-aminobenzo[d][1,3]dioxole-5-carboxylate

: 109773-42-4
3-(Triphenyl-λ⁵-phosphanylidene)-3H-[1,3]dioxolo[4,5-g]cinnolin-4-one

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / benzene / 6 h / 50 °C / Heating

2: n-pentyl nitrite, 36percent aq. HCl / methanol / 0.25 h / 0 °C

3: 10percent aq. NaOH / Ambient temperature

With hydrogenchloride; sodium hydroxide; n-Amyl nitrite; In methanol; benzene;
DOI:10.1055/s-1987-27921

Reference yield:

: 111054-06-9
1-(6-Amino-benzo[1,3]dioxol-5-yl)-2-(triphenyl-λ⁵-phosphanylidene)-ethanone

: 109773-42-4
3-(Triphenyl-λ⁵-phosphanylidene)-3H-[1,3]dioxolo[4,5-g]cinnolin-4-one

Guidance literature:: Multi-step reaction with 2 steps

1: n-pentyl nitrite, 36percent aq. HCl / methanol / 0.25 h / 0 °C

2: 10percent aq. NaOH / Ambient temperature

With hydrogenchloride; sodium hydroxide; n-Amyl nitrite; In methanol;
DOI:10.1055/s-1987-27921

Reference yield:

: 19493-09-5
Methylenetriphenylphosphorane

: 109773-42-4
3-(Triphenyl-λ⁵-phosphanylidene)-3H-[1,3]dioxolo[4,5-g]cinnolin-4-one

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / benzene / 6 h / 50 °C / Heating

2: n-pentyl nitrite, 36percent aq. HCl / methanol / 0.25 h / 0 °C

3: 10percent aq. NaOH / Ambient temperature

With hydrogenchloride; sodium hydroxide; n-Amyl nitrite; In methanol; benzene;
DOI:10.1055/s-1987-27921