HCCCH(OH)(CH₃)Co₂(CO)6

Base Information

• Chemical Name: HCCCH(OH)(CH₃)Co₂(CO)6
• CAS No.: 40687-04-5
• Molecular Formula: C₁₀H₆Co₂O₇
• Molecular Weight: 356.14
• Mol file: 40687-04-5.mol

Synonyms:

Chemical Property of HCCCH(OH)(CH₃)Co₂(CO)6

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HCCCH(OH)(CH₃)Co₂(CO)6

There total 1 articles about HCCCH(OH)(CH₃)Co₂(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

HCCCH(OH)(CH3)Co2(CO)5P(C6H5)3 → HCCCH(OH)(CH3)Co2(CO)6 (40687-04-5,172511-75-0) + HCCCH(OH)(CH3)Co2(CO)5P(C6H5)3 + HCCCH(OH)(CH3)*2Co*4CO*P(C6H5)3=HCCCH(OH)(CH3)Co2(CO)4P(C6H5)3

Guidance literature:

In not given; very slow react. in soln. at 20 °C accompanied by decompn.;

DOI:10.1021/om00104a044

Reference yield: 87.0%

HCCCH(OH)(CH3)Co2(CO)6 (40687-04-5,172511-75-0) → HCCCH(OH)(CH3)Co2(CO)5P(C6H5)3 (118576-64-0,118628-34-5) + HCCCH(OH)(CH3)*2Co*4CO*P(C6H5)3=HCCCH(OH)(CH3)Co2(CO)4P(C6H5)3

Guidance literature:

With triphenylphosphine; In tetrahydrofuran; diethyl ether; dropwise addn. of PPh3 soln. to soln. of hexacarbonyl complex at 50 °C; sepn. of diastereoisomers by flash chromy. over silica with Et2O/pentane; elem. anal.;

DOI:10.1021/om00104a044

Downstream raw materials:

HCCCH(OH)(CH₃)Co₂(CO)5P(C₆H₅)3