1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

Base Information

Chemical Name:1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol
CAS No.:160691-63-4
Molecular Formula:C₅₂H₆₈N₃O₁₃PSi
Molecular Weight:1002.18
Hs Code.:

1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

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Technology Process of 1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

There total 1 articles about 1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108549-23-1
Dibenzyl N,N-diisopropylphosphoramidite

: (3aS,4S,5S,5aR,8aS,8bS)-5-[(2R,3R,4R,5S,6R)-3-Azido-4,5-bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yloxy]-2,2,7,7-tetramethyl-hexahydro-benzo[1,2-d;3,4-d']bis[1,3]dioxol-4-ol

: 160691-63-4
1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

Guidance literature:: With 1H-tetrazole; ruthenium trichloride; sodium periodate; Yield given. Multistep reaction; 1.) CH₂Cl₂, MeCN, RT, 1 h, 2.) CH₂Cl₂, MeCN, 70 min;
DOI:10.1016/0008-6215(94)00178-2

Reference yield:

: 160691-63-4
1D-6-O-(2-azido-3,4-di-O-benzyl-2-deoxy-6-O-tert-butyldimethylsilyl-α-D-glucopyranosyl)-1-O-dibenzyloxyphosphoryl-2,3:4,5-di-O-isopropylidene-myo-inositol

: 129210-15-7
6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol 1-phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 16 mg / 1.1 M tetrabutylammonium fluoride / tetrahydrofuran / 2.5 h / Ambient temperature

2: 1.) H₂, 2.) Amberlite IR-120 (H⁺) / 1.) 10percent Pd/C / 1.) aq. EtOH, 18 h, 2.) MeOH, H₂O, RT, 1.5 h

With Amberlite IR-120 (H⁺); tetrabutyl ammonium fluoride; hydrogen; palladium on activated charcoal; In tetrahydrofuran;
DOI:10.1016/0008-6215(94)00178-2