(+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

Base Information

Chemical Name:(+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine
CAS No.:133744-49-7
Molecular Formula:C₃₃H₃₆N₂O₃S₂
Molecular Weight:572.792
Hs Code.:

Synonyms:

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Chemical Property of (+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

Chemical Property:

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Technology Process of (+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

There total 10 articles about (+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 536-59-4,18457-55-1
(-)-perillyl alcohol

: 133744-49-7
(+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

Guidance literature:: Multi-step reaction with 8 steps

1: 23.04 g / 4-pyrrolidinopyridine, pyridine / 1.) 0 deg C, 2 h, 2.) r.t., 14 h

2: 1.) Hg(OAc)2, 2.) NaBH₄, 2.5 N aq. NaOH / 1.) THF, H₂O, r.t., 5 h, 2.) 0 deg C, 30 min

3: 72 percent / HN₃, BF₃*OEt₂ / benzene / 3 h / Ambient temperature

4: NaHTe / diethyl ether; ethanol / 0.25 h / Ambient temperature

5: NaOMe / methanol / 3 h / Ambient temperature

6: Bu₃P, pyridine / 1.) 0 deg C, 30 min, 2.) r.t., 2 h

7: molecular sieves 3A / CHCl₃ / 2 h / Ambient temperature

8: dry HCOOH, molecular sieves 3A / CHCl₃ / 47 h / Ambient temperature

With pyridine; sodium hydroxide; sodium tetrahydroborate; formic acid; sodium hydrogen telluride; tributylphosphine; tris-(2-chloro-ethyl)-amine; 3 A molecular sieve; boron trifluoride diethyl etherate; mercury(II) diacetate; sodium methylate; 4-pyrrolidin-1-ylpyridine; In methanol; diethyl ether; ethanol; chloroform; benzene;
DOI:10.1002/hlca.19910740113

Reference yield:

: 133744-44-2
(S)-8-Hydroxy-p-menth-1-en-7-yl benzoate

: 133744-49-7
(+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

Guidance literature:: Multi-step reaction with 6 steps

1: 72 percent / HN₃, BF₃*OEt₂ / benzene / 3 h / Ambient temperature

2: NaHTe / diethyl ether; ethanol / 0.25 h / Ambient temperature

3: NaOMe / methanol / 3 h / Ambient temperature

4: Bu₃P, pyridine / 1.) 0 deg C, 30 min, 2.) r.t., 2 h

5: molecular sieves 3A / CHCl₃ / 2 h / Ambient temperature

6: dry HCOOH, molecular sieves 3A / CHCl₃ / 47 h / Ambient temperature

With pyridine; formic acid; sodium hydrogen telluride; tributylphosphine; tris-(2-chloro-ethyl)-amine; 3 A molecular sieve; boron trifluoride diethyl etherate; sodium methylate; In methanol; diethyl ether; ethanol; chloroform; benzene;
DOI:10.1002/hlca.19910740113

Reference yield:

: 133744-43-1
(S)-p-Mentha-1,8-dien-7-yl benzoate

: 133744-49-7
(+)-1-<(4-Methoxyphenyl)sulfonyl>-20-(phenylthio)hobartine

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) Hg(OAc)2, 2.) NaBH₄, 2.5 N aq. NaOH / 1.) THF, H₂O, r.t., 5 h, 2.) 0 deg C, 30 min

2: 72 percent / HN₃, BF₃*OEt₂ / benzene / 3 h / Ambient temperature

3: NaHTe / diethyl ether; ethanol / 0.25 h / Ambient temperature

4: NaOMe / methanol / 3 h / Ambient temperature

5: Bu₃P, pyridine / 1.) 0 deg C, 30 min, 2.) r.t., 2 h

6: molecular sieves 3A / CHCl₃ / 2 h / Ambient temperature

7: dry HCOOH, molecular sieves 3A / CHCl₃ / 47 h / Ambient temperature

With pyridine; sodium hydroxide; sodium tetrahydroborate; formic acid; sodium hydrogen telluride; tributylphosphine; tris-(2-chloro-ethyl)-amine; 3 A molecular sieve; boron trifluoride diethyl etherate; mercury(II) diacetate; sodium methylate; In methanol; diethyl ether; ethanol; chloroform; benzene;
DOI:10.1002/hlca.19910740113