[palladium⁽⁰⁾(triphenylphosphine)2(p-benzoquinone)]

Base Information

• Chemical Name: [palladium⁽⁰⁾(triphenylphosphine)2(p-benzoquinone)]
• CAS No.: 490039-51-5
• Molecular Formula: C₄₂H₃₄O₂P₂Pd
• Molecular Weight: 739.098
• Mol file: 490039-51-5.mol

Synonyms:

Chemical Property of [palladium⁽⁰⁾(triphenylphosphine)2(p-benzoquinone)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [palladium⁽⁰⁾(triphenylphosphine)2(p-benzoquinone)]

There total 2 articles about [palladium⁽⁰⁾(triphenylphosphine)2(p-benzoquinone)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + p-benzoquinone (106-51-4) → [palladium(0)(triphenylphosphine)2(p-benzoquinone)] (490039-51-5,57036-58-5)

Guidance literature:

In benzene; under N2 atm. to suspn. Pd(PPh3)4 in benzene was added soln. benzoquinone in benzene and stirred for 30 min; soln. was concd., ether-hexane was added;

DOI:10.1021/om0506419

Reference yield:

[Pd(η2:η2-p-benzoquinone)(η2:η2-1,5-cyclooctadiene)] (86228-56-0,1041752-88-8) → ((C6H5)3P)2Pd(C6H4O2) (57036-58-5,490039-51-5)

Guidance literature:

With triphenylphosphine; In chloroform; to soln. of educt in CHCl3 PPh3 in CHCl3 added at room temp., stirred for 10 min; evapd., solid washed with hexane, dried in vac.;

DOI:10.1016/0022-328X(83)80202-2

upstream raw materials:

[Pd(η2:η2-p-benzoquinone)(η2:η2-1,5-cyclooctadiene)]

tetrakis(triphenylphosphine) palladium⁽⁰⁾

p-benzoquinone