Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

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Chemical Name:Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester
CAS No.:109522-12-5
Molecular Formula:C₄₅H₅₁N₆O₁₅P₃
Molecular Weight:1008.85
Hs Code.:

Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

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Chemical Property of Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

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Technology Process of Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

There total 15 articles about Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 109522-11-4,145842-33-7
Phosphorous acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphanyloxy]-cyclohexyl ester

: 109522-12-5,112294-74-3,141040-51-9,145842-34-8,145842-35-9,147127-66-0
Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

Guidance literature:: With tert.-butylhydroperoxide;
DOI:10.1016/S0040-4039(00)96110-0

Reference yield: 67.0%

: Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6R)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphanyloxy]-cyclohexyl ester

: 109522-12-5,112294-74-3,141040-51-9,145842-34-8,145842-35-9,147127-66-0
Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

Guidance literature:: DOI:10.1016/0008-6215(92)85046-3

Reference yield:

: 98906-30-0,104873-76-9,111466-07-0,114297-88-0,114297-91-5,114419-08-8,115184-71-9,115509-75-6,115509-76-7,118354-54-4,118354-55-5,128163-34-8,129706-80-5,136521-84-1,149713-88-2,149713-95-1
(±)-2,3,6-tri-O-benzyl-myo-inositol

: 109522-12-5,112294-74-3,141040-51-9,145842-34-8,145842-35-9,147127-66-0
Phosphoric acid bis-(2-cyano-ethyl) ester (1R,2R,3S,4R,5R,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphoryloxy]-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-tetrazole / acetonitrile; CH₂Cl₂ / Ambient temperature

2: t-BuOOH / CH₂Cl₂; 2,2,4-trimethyl-pentane / 1) -20 deg C -> room temperature, 2) room temperature

With 1H-tetrazole; tert.-butylhydroperoxide; In 2,2,4-trimethylpentane; dichloromethane; acetonitrile;
DOI:10.1016/S0040-4020(97)00714-X