RuCl(CCC₆H₅)[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2

Base Information

• Chemical Name: RuCl(CCC₆H₅)[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2
• CAS No.: 315197-05-8
• Molecular Formula: C₄₈H₄₅ClP₄Ru
• Molecular Weight: 882.303
• Mol file: 315197-05-8.mol

Synonyms:

Chemical Property of RuCl(CCC₆H₅)[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCl(CCC₆H₅)[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2

There total 1 articles about RuCl(CCC₆H₅)[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

RuCl2[C6H5(CH3)PC6H4P(CH3)C6H5]2 (82373-48-6,82442-81-7,82338-48-5,82373-45-3,315662-12-5,82467-17-2,82373-46-4,82442-77-1,82373-49-7,82442-78-2,82443-57-0) + phenylacetylene (536-74-3) → RuCl(CCC6H5)[C6H5(CH3)PC6H4P(CH3)C6H5]2 (315197-05-8)

Guidance literature:

With sodium hexaflorophosphate; triethylamine; In toluene; (N2); refluxing a mixt. of ruthenium complex with alkyne and NaPF6 in toluene for 4 h, dissolving ppt. in CH2Cl2, addn. of NEt3 dropwise with stirring,; column chromy (Al2O3, CH2Cl2), evapn., elem. anal.;

DOI:10.1016/S0022-328X(00)00420-4

upstream raw materials:

RuCl₂[C₆H₅(CH₃)PC₆H₄P(CH₃)C₆H₅]2

phenylacetylene

Refernces