Monomethyl carbonotrithioate

Base Information

• Chemical Name: Monomethyl carbonotrithioate
• CAS No.: 1113-26-4
• Molecular Formula: C2H4S3
• Molecular Weight: 123.24000
• Hs Code.: 2930909090
• Mol file: 1113-26-4.mol

Synonyms:Methylthioxanthogensaeure;Methyltrithiokohlensaeure;Monomethyl carbonotrithioate;

Chemical Property of Monomethyl carbonotrithioate

Chemical Property:

• Melting Point: 126-128 °C
• Boiling Point: 88-91 °C(Press: 5 Torr)
• PKA: 3.48±0.60(Predicted)
• PSA: 57.39000
• Density: 1.2538 g/cm3
• LogP: 1.18120

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Methylthioxanthic Acid is an impurity of?Telmisartan (T017000), an angiotensin II receptor antagonist.

Technology Process of Monomethyl carbonotrithioate

There total 2 articles about Monomethyl carbonotrithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + sodium thiomethoxide (5188-07-8) → Methyl-thioxanthogensaeure (1113-26-4)

Guidance literature:

With hydrogenchloride; In diethyl ether; at 0 ℃; 1.) 2 h;

DOI:10.1002/hlca.19940770721

Reference yield:

→ Methyl-thioxanthogensaeure (1113-26-4)

Guidance literature:

entspr. Thioxanthat, HCl;

DOI:10.1002/zaac.19784420125

Reference yield:

Methyl-thioxanthogensaeure (1113-26-4) + 2,2-dimethyl-3-(N-methyl-N-phenylamino)-2H-azirine (75755-40-7) → S-methyl-N-<1-methyl-1-(N-methyl-N-phenylthiocarbamoyl)ethyl>dithiocarbamate (160318-91-2)

Guidance literature:

In diethyl ether; Yield given; 0 deg C, 20 min then r.t.;

DOI:10.1002/hlca.19940770721

upstream raw materials:

carbon disulfide

sodium thiomethoxide

Downstream raw materials:

S-methyl-N-<1-methyl-1-(N-methyl-N-phenylthiocarbamoyl)ethyl>dithiocarbamate

Refernces

• 1、 Shi,Linden,Heimgartner. "Synthesis and reactions of 2-(alkylthio)-4,4-dimenthyl-1,3-thiazole-5(4H)-thiones". . p. 1903 - 1920. Retrieved 2007/10/02.