Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

Base Information

Chemical Name:Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)
CAS No.:102234-29-7
Molecular Formula:C₂₀H₁₈Fe₂O₂SSe
Molecular Weight:513.082
Hs Code.:

Synonyms:

Suppliers and Price of Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

There total 2 articles about Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 76189-80-5
{Cp2Fe2(CO)2(μ-CO)(μ-CSMe)}PF6

: 1666-13-3
diphenyl diselenide

: 102234-29-7
Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

: Cp₂Fe₂(CO)3(CS)

Guidance literature:: With Na#Hg; In tetrahydrofuran; react. of PhSeSePh soln. with Na-Hg, filtration through Celite, cooling to 0 °C, react. with Cp2Fe2(CO)3 ; all operations under N2; evapn. in vacuo at 0 °C, extn. with hexane to remove Ph2Se2 and Cp2Fe2(CO)3(CS), dissolution of residue in CH2Cl2, filtration through Celite, concn., layering with hexane and crystn. at -20 °C; IR and elem. anal.;

Reference yield: 31.0%

: (C₅H₅)2Fe₂(CO)2(CO)(CSCH₃)

: 1666-13-3
diphenyl diselenide

: 102234-29-7
Cp2Fe2(SePh)(CO)(μ-CO)(μ-CSMe)

: Cp2Fe2(CO)2(μ-CO){μ-C(SMe)SePh}

Guidance literature:: In tetrahydrofuran; PhSeSePh was added to the Fe-radical in THF at -80°C, warmed to -20°C gave Cp2Fe2(CO)3(C(SMe)SePh), the soln. was warmed to room temp., the solvent was removed under vac.; the residue was washed with hexane and extd. with CH2Cl2, filtered, concd. at -20°C gave Cp2Fe2(SePh)(CO)2(CSMe);;
DOI:10.1021/ja00273a023