cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate

Base Information

• Chemical Name: cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate
• CAS No.: 89199-63-3
• Molecular Formula: C₃₀H₂₅FeOPS
• Molecular Weight: 520.415

Synonyms:

Chemical Property of cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate

Chemical Property:

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Technology Process of cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate

There total 8 articles about cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

ammonium hexafluorophosphate + (C5H5)Fe(CO)2SC6H5(AlBr3) → CpFe(CO)3SC6H5 (12110-44-0) + (η5-C5H5)Fe(CO)2(triphenylphosphino) hexafluorophosphate + cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate (89199-63-3)

Guidance literature:

With triphenylphosphine; In dichloromethane; Fe-complex was combined in CH2Cl2 with 1 equiv of PPh3 under Ar, mixt. was stirred at room temp. for 24 h; evapd. under vac., residue hydrolyzed with H2O, filtered, 2 equiv of NH4PF6 added to the filtrate (cationic complex pptd.), ppt. left on the filter was extd. into CH2Cl2, sepd. on an alumina column (Et2O-CH2Cl2); identified by (1)H NMR and IR spectra;

DOI:10.1016/0022-328X(85)87234-X

Reference yield: 35.0%

ammonium hexafluorophosphate + (C5H5)Fe(CO)2SC6H5(Al(CH3)3) → CpFe(CO)3SC6H5 (12110-44-0) + (η5-C5H5)Fe(CO)2(triphenylphosphino) hexafluorophosphate + cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate (89199-63-3)

Guidance literature:

With triphenylphosphine; In dichloromethane; Fe-complex was combined in CH2Cl2 with 1 equiv of PPh3 under Ar, mixt. was stirred at room temp. for 24 h, reaction was monitored by IR spectroscopy; evapd. under vac., residue hydrolyzed with H2O, filtered, 2 equiv of NH4PF6 added to the filtrate (cationic complex pptd.), ppt. left on the filter was extd. into CH2Cl2, sepd. on an alumina column (Et2O-CH2Cl2); identified by (1)H NMR and IR spectra;

DOI:10.1016/0022-328X(85)87234-X

Reference yield: 20.0%

ammonium hexafluorophosphate + CpFe(CO)3SC6H5 (12110-44-0) → (η5-C5H5)Fe(CO)2(triphenylphosphino) hexafluorophosphate + cyclopentadienyl iron carbonyl triphenylphosphine thiophenylate (89199-63-3)

Guidance literature:

With triphenylphosphine; In dichloromethane; Fe-complex was combined in CH2Cl2 with 1 equiv of PPh3 under Ar, mixt. was stirred at room temp. for 24 h; 80% of unreacted initial complex wasisolated after the reaction; evapd. under vac., residue hydrolyzed with H2O, filtered, 2 equiv of NH4PF6 were added to the filtrate (no ppt. was observed), ppt. left on thefilter was extd. into CH2Cl2, sepd. on an alumina column (Et2O-CH2Cl2);identified by (1)H NMR and IR spectra;

DOI:10.1016/0022-328X(85)87234-X

upstream raw materials:

CpFe(CO)3SC6H5

Downstream raw materials:

[(η5-C5H5)Fe(PhSEt)(CO)(PPh3)]Br

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