[Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO₄

Base Information

• Chemical Name: [Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO₄
• CAS No.: 72476-81-4
• Molecular Formula: C₂₈H₃₀ClOP₂PdS*ClO₄
• Molecular Weight: 717.883
• Mol file: 72476-81-4.mol

Synonyms:

Chemical Property of [Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO₄

There total 1 articles about [Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) (19978-61-1) + silver perchlorate + dimethyl sulfoxide (67-68-5,8070-53-9) → [Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO4 (72476-81-4) + [(Pd(1,2-bis(diphenylphosphino)ethane)Cl)2](ClO4)2 (72476-84-7)

Guidance literature:

In dichloromethane; dimethyl sulfoxide; byproducts: AgCl; addn. of 1 equiv. AgClO4 (in DMSO) to Pd-complex (in CH2Cl2), stirring (15 min); filtration, partial evapn. (vac.), pptn. on Et2O addn., dissoln. in CH2Cl2, filtration, pptn. on Et2O addn., filtration, washing (EtOH, Et2O), drying in air; elem. anal.; impurity of dimeric complex not sepd., detd. by IR spectroscopy;

DOI:10.1039/DT9790001705

Reference yield: 100.0%

[Pd(1,2-bis(diphenylphosphino)ethane)(dimethyl sulphoxide)Cl]ClO4 (72476-81-4) → [(Pd(1,2-bis(diphenylphosphino)ethane)Cl)2](ClO4)2 (72476-84-7)

Guidance literature:

In neat (no solvent); 78°C, 1E-3 Torr, 7 days;

DOI:10.1039/DT9790001705

upstream raw materials:

(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

dimethyl sulfoxide

Downstream raw materials:

[(Pd(1,2-bis(diphenylphosphino)ethane)Cl)2](ClO₄)2