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Technology Process of (C5H5)3Rh3(CO)(C6H5C2C6H4CH3)

(C5H5)3Rh3(CO)(C6H5C2C6H4CH3)

Base Information
  • Chemical Name:(C5H5)3Rh3(CO)(C6H5C2C6H4CH3)
  • CAS No.:88801-71-2
  • Molecular Formula:C31H27ORh3
  • Molecular Weight:724.271
  • Hs Code.:
(C<sub>5</sub>H<sub>5</sub>)3Rh<sub>3</sub>(CO)(C<sub>6</sub>H<sub>5</sub>C<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)

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Chemical Property of (C5H5)3Rh3(CO)(C6H5C2C6H4CH3)
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Technology Process of (C5H5)3Rh3(CO)(C6H5C2C6H4CH3)

There total 1 articles about (C5H5)3Rh3(CO)(C6H5C2C6H4CH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trirhodium (μ2-carbonyl)3(η5-Cp)3

trirhodium (μ2-carbonyl)3(η5-Cp)3

4-(phenylethynyl)toluene
3287-02-3

4-(phenylethynyl)toluene

(C<sub>5</sub>H<sub>5</sub>)3Rh<sub>3</sub>(CO)(C<sub>6</sub>H<sub>5</sub>C<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)
88801-71-2

(C5H5)3Rh3(CO)(C6H5C2C6H4CH3)

Guidance literature:
In benzene; Irradiation (UV/VIS); benzene was added to a mixt. of alkyne and Rh3-cluster, soln. was rapidly stirred under N2 bubbling for several min, photolyzed (quartz vessel)for 13 h; benzene was removed in vacuo, residue chromd. over neutral alumina (eluent benzene), recrystd. from CH2Cl2-MeOH;
DOI:10.1021/om00082a020

Reference yield: 45.0%

(C<sub>5</sub>H<sub>5</sub>)3Rh<sub>3</sub>(CO)(C<sub>6</sub>H<sub>5</sub>C<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)
88801-71-2

(C5H5)3Rh3(CO)(C6H5C2C6H4CH3)

(C<sub>5</sub>H<sub>5</sub>)3Rh<sub>3</sub>(CC<sub>6</sub>H<sub>5</sub>)(CC<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)
88801-73-4

(C5H5)3Rh3(CC6H5)(CC6H4CH3)

Guidance literature:
In neat (no solvent, gas phase); cluster was subjected to flash vac. pyrolysis at 500°C and <10E-5 Torr in a quartz tube; starting complex was isolated with 39% recovery; products were condensed on a cold finger at -196°C, brought intosoln. under N2, sepd. by column chromy. over neutral alumina (eluent benzene followed by benzene-CH2Cl2), benzene eluate was evapd., residue recrystd. from CH2Cl2-MeOH;
DOI:10.1021/om00082a020
upstream raw materials:

4-(phenylethynyl)toluene

Downstream raw materials:

(C5H5)3Rh3(CC6H5)(CC6H4CH3)

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