(4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate

Base Information

• Chemical Name: (4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate
• CAS No.: 104337-66-8
• Molecular Formula: BF₄*C₅₃H₆₄N₂O₅P₂RhSi
• Molecular Weight: 1088.84
• Mol file: 104337-66-8.mol

Synonyms:

Chemical Property of (4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate

There total 2 articles about (4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate + 4-<(3R,4R)-3,4-Bis(diphenylphosphino)pyrrolidinocarbonyl>-N-<3-(triethoxysilyl)propyl>benzamid (104373-42-4) → (4-[(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidinocarbonyl]-N-[3-(triethoxysilyl)propyl]benzamide-P,P')(1,5-cyclooctadiene)rhodium-tetrafluoroborate (104337-66-8)

Guidance literature:

In dichloromethane; (N2), dissolved compounds mixed, stirred for 2 h; volume reduced, precipitated with Et2O, centrifuged, washed with Et2O, dried in vac.; elem. anal.;

Reference yield:

rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate + (P(C6H5)2)2C4NH6COC6H4CONH(CH2)3Si(OC2H5)3 → [Rh(C8H12)((P(C6H5)2)2C4NH6COC6H4CONH(CH2)3Si(OC2H5)3)](1+)*BF4(1-) (104337-66-8)

Guidance literature:

In not given;

DOI:10.1039/c39860001098

upstream raw materials:

4-<(3R,4R)-3,4-Bis(diphenylphosphino)pyrrolidinocarbonyl>-N-<3-(triethoxysilyl)propyl>benzamid