benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Base Information

Chemical Name:benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide
CAS No.:171423-26-0
Molecular Formula:C₄₁H₃₇N₇O₇S₂
Molecular Weight:803.919
Hs Code.:

benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Synonyms:

Suppliers and Price of benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

There total 3 articles about benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: benzhydryl 2β-(azidomethyl)-2α-methylpenam-3α-carboxylate 1,1-dioxide

: 171423-26-0
benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Guidance literature:: Multi-step reaction with 3 steps

1: 55 percent / 1,2-dimethoxy-ethane / 18 h / 50 °C

2: 78 percent / diisobutylaluminium hydride / tetrahydrofuran / 2.5 h / -60 °C

3: 1.) trifluoromethane silfonic anhydride, triethylamine, 2.) potassium tert-butoxide / 1.) methylene chloride, -40 deg C, 1 h, 2.) -40 deg C, 1 h, room temperature, 1 h

With trifluoromethylsulfonic anhydride; potassium tert-butylate; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; 1,2-dimethoxyethane;
DOI:10.7164/antibiotics.48.1320

Reference yield:

: 98382-61-7
benzhydryl 2β-<(4-carboxaldehyde)-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

: 171423-26-0
benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / diisobutylaluminium hydride / tetrahydrofuran / 2.5 h / -60 °C

2: 1.) trifluoromethane silfonic anhydride, triethylamine, 2.) potassium tert-butoxide / 1.) methylene chloride, -40 deg C, 1 h, 2.) -40 deg C, 1 h, room temperature, 1 h

With trifluoromethylsulfonic anhydride; potassium tert-butylate; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran;
DOI:10.7164/antibiotics.48.1320

Reference yield:

: 136933-57-8
2,5-dihydro-6-diphenylmethyloxy-3-mercapto-2-methyl-5-oxo-1,2,4-triazin

: 171423-22-6
benzhydryl 2β-<(4-hydroxymethyl)-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

: 171423-26-0
benzhydryl 2β-<<4-(2,5-dihydro-6-benzhydryloxy-2-methyl-5-oxo-as-triazin-3-ylthiomethyl)>-1,2,3-triazol-1-yl>methyl-6,6-dihydropenicillanate 1,1-dioxide

Guidance literature:: With trifluoromethylsulfonic anhydride; potassium tert-butylate; triethylamine; Yield given. Multistep reaction; 1.) methylene chloride, -40 deg C, 1 h, 2.) -40 deg C, 1 h, room temperature, 1 h;
DOI:10.7164/antibiotics.48.1320