benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate

Base Information

• Chemical Name: benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate
• CAS No.: 1353682-17-3
• Molecular Formula: C₁₈H₂₃NO₂
• Molecular Weight: 285.386
• Mol file: 1353682-17-3.mol

Synonyms:

Chemical Property of benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate

There total 1 articles about benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,4,5,5-tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane (865350-17-0) + N-(cyclohexyl(methoxy)methyl)benzyl carbamate (1353682-09-3) → benzyl (R)-1-cyclohexylbuta-2,3-dienylczrbamate + benzyl (S)-1-cyclohexylbuta-2,3-dienylczrbamate (1353682-17-3) + benzyl 1-cyclohexylbut-3-ynylcarbamate + benzyl 1-cyclohexylbut-3-ynylcarbamate

Guidance literature:

With indium chloride; (R)-3,3'-bis(3,5-di-tert-butyl-4-methoxyphenyl)-1,1'-binaphthyl-2,2'-dihydrogenphosphonate, silver; In cyclopentyl methyl ether; toluene; at 23 ℃; for 24h; optical yield given as %ee; regioselective reaction; Inert atmosphere; Darkness;

DOI:10.1002/anie.201105182

upstream raw materials:

4,4,5,5-tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane

N-(cyclohexyl(methoxy)methyl)benzyl carbamate