Stannane, tributyl-2-cyclohexen-1-yl-

Base Information

Chemical Name:Stannane, tributyl-2-cyclohexen-1-yl-
CAS No.:112520-99-7
Molecular Formula:C₁₈H₃₆Sn
Molecular Weight:371.194
Hs Code.:
DSSTox Substance ID:DTXSID50454074
Mol file:112520-99-7.mol

Synonyms:Stannane, tributyl-2-cyclohexen-1-yl-;112520-99-7;TRIBUTYL(CYCLOHEX-2-EN-1-YL)STANNANE;tri-n-butyl-2-cyclohexenyltin;DTXSID50454074;GJBCTVKWKFFLEY-UHFFFAOYSA-N;tri-n-butyl-2-cyclohexen-1-yl-tin;tri-n-butyl(cyclohex-2-enyl)stannane

Suppliers and Price of Stannane, tributyl-2-cyclohexen-1-yl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Stannane, tributyl-2-cyclohexen-1-yl-

Chemical Property:

PSA：0.00000
LogP:5.87640
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:372.183904
Heavy Atom Count:19
Complexity:222

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1CCCC=C1

Technology Process of Stannane, tributyl-2-cyclohexen-1-yl-

There total 3 articles about Stannane, tributyl-2-cyclohexen-1-yl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 688-73-3
tri-n-butyl-tin hydride

: 1165952-91-9
cyclohexa-1,3-diene

: 112520-99-7,1177092-71-5
tributyl(cyclohex-2-en-1-yl)stannane

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ol4005257

Reference yield: 82.0%

: 76644-52-5,76704-31-9,14447-34-8,62247-41-0
rac-3-acetoxycyclohexene

: 1067-52-3
tributyltin methoxide

: 112520-99-7,1177092-71-5
tributyl(cyclohex-2-en-1-yl)stannane

Guidance literature:: With manganese; chloro-trimethyl-silane; 4,4'-di-tert-butyl-2,2'-bipyridine; nickel dibromide; In N,N-dimethyl-formamide; at 25 ℃; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1002/chem.201601515

Reference yield: 59.0%

: 1461-22-9
tributyltin chloride

: 1521-51-3,113667-32-6
rac-3-bromocyclohexene

: 112520-99-7,1177092-71-5
tributyl(cyclohex-2-en-1-yl)stannane

Guidance literature:: With ammonium chloride; zinc; In tetrahydrofuran; water; appropriate alkyltin chloride is added to THF/H2O mixt. with excess of zinc powder, appropriate allyl bromide is added dropwise under stirring within 5 min, mixt. is stirred for 30 min; extn. (petroleum ether), separated org. layer is washed (aq. NaCl), drying (MgSO4), solvent is removed, distn.;
DOI:10.1021/om00015a025