(+)-Fusarinolic acid

Base Information

Chemical Name:(+)-Fusarinolic acid
CAS No.:33130-74-4
Molecular Formula:C₁₀H₁₃NO₃
Molecular Weight:195.218
Hs Code.:
DSSTox Substance ID:DTXSID101017471
Nikkaji Number:J1.051.333B
Mol file:33130-74-4.mol

Synonyms:(+)-Fusarinolic acid;33130-74-4;DTXSID101017471

Suppliers and Price of (+)-Fusarinolic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (+)-Fusarinolic acid

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:195.08954328
Heavy Atom Count:14
Complexity:196

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(CCC1=CN=C(C=C1)C(=O)O)O
Isomeric SMILES:C[C@@H](CCC1=CN=C(C=C1)C(=O)O)O

Technology Process of (+)-Fusarinolic acid

There total 11 articles about (+)-Fusarinolic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 328385-67-7
benzyl (S)-5-(3-hydroxy-but-1-ynyl)pyridine-2-carboxylate

: 33130-74-4
(S)-(+)-fusarinolic acid

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 6h; under 2068.65 Torr;
DOI:10.1021/jo0013554

Reference yield: 82.0%

: 215436-40-1
5-((S)-3-Hydroxy-butyl)-pyridine-2-carboxylic acid methyl ester

: 33130-74-4
(S)-(+)-fusarinolic acid

Guidance literature:: With potassium hydroxide; In methanol; water; at 0 ℃; for 2h;
DOI:10.1021/jo981014e

Reference yield:

: 624-28-2
2,5-dibromopyridine

: 33130-74-4
(S)-(+)-fusarinolic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / NaI; AcCl / acetonitrile / 3 h / Heating

2: 93 percent / TEA / Pd(PPh₃)2Cl₂ / 15 h / 60 °C / 3102.97 Torr

3: 92 percent / TEA / Pd(PPh₃)4 / tetrahydrofuran / 15 h / 70 °C

4: 96 percent / H₂ / Pd/C / methanol / 6 h / 2068.65 Torr

With TEA; hydrogen; acetyl chloride; sodium iodide; bis-triphenylphosphine-palladium(II) chloride; palladium on activated charcoal; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol; acetonitrile;
DOI:10.1021/jo0013554