tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

Base Information

Chemical Name:tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)
CAS No.:119407-36-2
Molecular Formula:C₃₆H₄₄Ru
Molecular Weight:577.815
Hs Code.:

Synonyms:

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Chemical Property of tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

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Technology Process of tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

There total 2 articles about tetrakis(2,4,6-trimethylphenyl)ruthenium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: tetra-μ-acetato-ruthenium(II)

: 2633-66-1
2-mesitylmagnesium bromide

: 119407-36-2
tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

Guidance literature:: In tetrahydrofuran; diethyl ether; under Ar, addn. of (CH3)3C4H2MgBr in Et2O to a soln of Ru2(O2CCH3)4 in THF at -78°C, warmed slowly, stirred at room temp. for 1 h; evapn., extn. (hexane), filtered, evapd., extn. (diethyl ether), addn. of water, stirred for 0.5 h, filtered onto MgSO4 at -10°C, stirred for 1 h, filtered, concd., extn. (hexane), cooled overnight (-20°C); elem. anal.;

Reference yield: 18.4%

: Mg(C₆H₂Me₃-2,4,6)2(tetrahydrofuran)2

: 131679-77-1
RuCl₃(tetrahydrothiophen)3

: 119407-36-2
tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

Guidance literature:: In tetrahydrofuran; diethyl ether; addn. of a soln. of the Mg compd. in THF to a soln. of the complex in Et2O (-78°C, vigorous stirring), warmed, stirred (room temp.); evapn. (vac.), extd. (light petroleum, 40-60°C), concd., filtered, cooled (-30°C), crystn.; elem. anal.;
DOI:10.1039/DT9920003477

Reference yield: 69.0%

: 119407-36-2
tetrakis(2,4,6-trimethylphenyl)ruthenium(IV)

: tetrakis(mesityl)ruthenium(V) hexafluorophosphate

Guidance literature:: With NOPF₆; In dichloromethane; addn. of a soln. of NOPF6 to a soln. of the complex, stirred (0.5 h); evapn., dissoln. in min. amt. of MeCN, addn. of Et2O, cooled (-30°C); elem. anal.;
DOI:10.1039/DT9920003477