dihydroxoruthenium(VI) tetramesitylporphyrin complex

Base Information

Chemical Name:dihydroxoruthenium(VI) tetramesitylporphyrin complex
CAS No.:152600-35-6
Molecular Formula:C₅₆H₅₄N₄O₂Ru
Molecular Weight:916.14
Hs Code.:

Synonyms:

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Chemical Property of dihydroxoruthenium(VI) tetramesitylporphyrin complex

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Technology Process of dihydroxoruthenium(VI) tetramesitylporphyrin complex

There total 1 articles about dihydroxoruthenium(VI) tetramesitylporphyrin complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92669-43-7
(carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)

: 152600-35-6
dihydroxoruthenium(VI) tetramesitylporphyrin complex

Guidance literature:: With m-chloroperoxybenzoic acid; H₂O; In ethanol; dichloromethane; addn. of the peroyxbenzoic acid to a CH2Cl2/EtOH (1:2) soln. of the Ru complex, filtration and standing at room temp. overnight; crystn., collecting, washing (cold ethanol), concg. the filtrate, second crop of the product complex, contamination with unreacted peroxybenzoic acid;
DOI:10.1016/S0277-5387(00)83049-1

Reference yield:

: 152600-35-6
dihydroxoruthenium(VI) tetramesitylporphyrin complex

: 92669-44-8
dioxo(tetramesitylporphyrinato)ruthenium(VI)

Guidance literature:: With air; In dichloromethane; air oxidation of the dihydroxo Ru complex in CH2Cl2; indicated by 1H NMR;
DOI:10.1016/S0277-5387(00)83049-1

Reference yield:

: 152600-35-6
dihydroxoruthenium(VI) tetramesitylporphyrin complex

: 14797-71-8
¹⁸O-labeled water

: dihydroxoruthenium(VI) tetramesitylporphyrin complex

Guidance literature:: In ethanol; dichloromethane; prepn. of the labeled complex on recrystn. from CH2Cl2/EtOH/H2(18)O (20:20:1);
DOI:10.1016/S0277-5387(00)83049-1